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中文摘要：
通过改进的溶胶-凝胶工艺在低温（800℃）下合成了基于钛酸锌（ZnTiO3）体系的（Zn1-xCox）TiO3、（Zn1-xNix）TiO3和[Zn1-x（Co0.5Ni0.5）x]TiO3陶瓷固溶体。采用X射线衍射分析（XRD）和差示扫描量热法（DSC）等测量技术对产物进行了物相和热稳定性分析。XRD结果表明，获得单一六方相（Zn1-xCox）TiO3、（Zn1-xNix）TiO3和[Zn1-x（Co0.5）xNi0.5]TiO3时各自的固溶稳定区间为0．5≤x≤1．0，0．9≤x≤1．0和0．8≤x≤1．0。与此同时，热分析结果证实，伴随钛酸锌基陶瓷体系掺杂钴量的增加，其六方相的热稳定性提高，且效果比掺杂镍更加显著。
英文摘要：
The solid solution of （Zn1-xCox）TiO3,（Zn1-xNix）TiO3 and [Zn1-x（Co0.5Ni0.5）x]TiO3 based on ZnTiO3 system were synthesized at low temperature （800 ℃） by a modified sol-gel route. The phase distribution and thermal stability of these products were conducted by using X-ray diffraction （XRD） analysis and differential scanning calorimetry （DSC） measurements. The XRD results showed that the single phase of hexagonal （Zn1-xCox）TiO3, （Zn1-xNix）TiO3, and [Zn1-x（Co0.5Ni0.5）]TiO3 could only be obtained at 0.5 ≤ x ≤1, 0.9≤x ≤1 and 0.8 ≤ x ≤ 1, respectively. Meanwhile, the thermal analysis results indicated that the thermal stability of these ZnTiO3-based ceramics Were enhanced by the increasing amount of cobalt substitution, and that cobalt substitution than nickel substitution. appeared more remarkably than nickel substitution.
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