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三维杂金属（3d-4f）配位聚合物： {[Ln2Cu（pydc）4（H2O）6]·2H2O}n的合成与结构
  • ISSN号：0023-074X
  • 期刊名称：《科学通报》
  • 时间：0
  • 分类：O614.711[理学—无机化学;理学—化学] O614.121[理学—无机化学;理学—化学]
  • 作者机构：[1]兰州大学化学化工学院甘肃省有色金属化学与资源利用重点实验室,兰州730000
  • 相关基金：国家自然科学基金资助项目（批准号：20771048,20621091）
作者： 马景新[1], 黄肖锋[1], 魏瑞平[1], 刘伟生[1]
关键词： 3d-4f金属配位聚合物2, 5-吡啶二甲酸晶体结构
中文摘要：

在水热条件下（160℃）, 通过稀土氧化物（Ln2O3）、氯化铜（CuCl2）与2,5-吡啶二甲酸（H2pydc）反应合成了两个新颖的3d-4f配位聚合物{[Ln2Cu（pydc）4（H2O）6]？2H2O}n [Ln = Eu（1）和Gd（2）]. X射线晶体学研究表明, 配位聚合物（1）和（2）是同晶异质体, 都具有开放的三维网状结构. 晶体结构和热重分析结果都表明在配位聚合物内存在较强的氢键相互作用.

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期刊信息
  • 《科学通报》
  • 北大核心期刊（2011版）
  • 主管单位:中国科学院
  • 主办单位:中国科学院
  • 主编：周光召
  • 地址：北京东黄城根北街16号
  • 邮编：100717
  • 邮箱：csb@scichina.org
  • 电话：010-64036120 64012686
  • 国际标准刊号：ISSN：0023-074X
  • 国内统一刊号：ISSN：11-1784/N
  • 邮发代号:80-213
  • 获奖情况:
  • 首届国家期刊奖,中国期刊方阵“双高”期刊,第三届中国出版政府奖
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  • 被引量:81792