地下水年龄是水文地质研究的重要参数,特别是年轻地下水的年龄。论述了安装设计的用于地下水中SF6的测试技术,该技术装置由SF6提取系统和分析测试系统两部分组成,前者由剥离器、硅胶管、冷冻富集陷阱、六通阀、十通阀、高纯氮气钢瓶和载气过滤系统组成,后者由带电子捕获检测器(ECD)的气相色谱仪组成。通过条件实验,该系统测定SF6的标准误差为1.77%,对SF6的最低检测极限为1.0×10^-12,测定空气中的SF6只需10mL气体,测定地下水样时只需1.0L。研究了地下水SF6年龄的计算程序,计算了石家庄市浅层地下水的年龄。
Groundwater age, especially the young groundwater age, is an important parameter. The testing method of dating young groundwater with SF6 is designed and installed. It is unitized in two parts: distilling system and testing system. The former system is made up of stripper, silicone tube, freezing and enrichment trap, six-way valve, ten-way valve, high-purity nitrogen tube. The latter is a gas-phase chromatographic apparatus with electronic catcher detector. By condition experiment, the standard error of this testing method is 1.77%, the minimum of detecting SF6 is 1.0×10^-12, Only 10.0 mL air is needed in determiningthe SF6 of air, and 1.0 L water in determining the SF6 in the ground water. Besides, the shallow groundwater in Shijiazhuang city is dated by the program of calculating SF6 age.