将染料分子与半导体表面所组成的异质结与金属纳米粒子的耦合系统作为研究对象,考虑分子的振动态,在偶极-偶极近似下研究其线性吸收谱及相关的电荷转移动力学过程. 对金属纳米粒子作用下吸收谱变宽及相关的电子转移增强过程作了仔细的分析和讨论,理论分析了金属钠米粒子的表面等离激元对异质结中超快电子转移的影响.
By considering the effect of molecular vibrational states, a system of dye semi-conductor coupled with metal nano-particle linear absorption spectra and its electron transfer dynamics are studied in dipole-dipole approximation. As the results of the coupling of metal nano-particle, a wider absorption spectrum and the enhancement of electron transfer have been achieved. Effects of nano-metal surface plasmons on the ultrafast heterogeneous electron transfer are discussed in detail.