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Regulation of Superoxide Anion Radical During the Oxygen Delignification Process
  • ISSN号:1004-9541
  • 期刊名称:Chinese Journal of Chemical Engineering
  • 时间:0
  • 页码:141-144
  • 语言:英文
  • 分类:TS749.3[轻工技术与工程—制浆造纸工程]
  • 作者机构:[1]State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510641 China, [2]Institute of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002, China
  • 相关基金:Supported by the National Natural Science Foundation of China (No.20477046), the Natural Science Foundation of Fujian Province of China (No.2004HZ03-5) and the Young Scientist Innovation Foundation of Fujian Province of China (No.2006F3009).
  • 相关项目:竹纤维增强聚酰胺树脂复合材料界面优化设计
中文摘要:

在这研究,超级氧化物阴离子激进分子被 1,2,3-trihydroxybenzene 的汽车氧化产生并且由紫外 spectrophotometry,和反应决定了被发现被 anthraquinone-2-sulfonic 酸钠盐便于。竹子牛皮纸浆被 1,2,3-trihydroxybenzene 汽车氧化方法对待或 1,2,3-trihydroxybenzene 汽车氧化与 anthraquinone-2-sulfonic 酸钠盐结合了在牛皮纸浆并且提高在 delignification 上作为添加剂蒽醌混合物影响的竹子的氧 delignification 期间显示出超级氧化物阴离子激进分子的效果。结果显示超级氧化物阴离子激进分子能与木质素反应并且在纤维素,和 an-thraquinone-2-sulfonic 酸钠盐上与可以忽略的损坏把它从肉移开能便于超级氧化物阴离子基的产生提高肉的 delignification。氧 delignification 选择能用与 anthraquinone-2-sulfonic 酸钠盐相结合的 1,2,3-trihydroxybenzene 汽车氧化系统被改进。

英文摘要:

In this study, the superoxide anion radicals were generated by the auto-oxidation of 1,2,3-trihydroxybenzene and determined by UV spectrophotometry, and the reaction was found to be facilitated by anthraquinone-2-sulfonic acid sodium salt. The bamboo kraft pulps were treated by the 1,2,3-trihydroxybenzene auto-oxidation method or the 1,2,3-trihydroxybenzene auto-oxidation combined with anthraquinone-2-sulfonic acid sodium salt to show the ef- fect of the superoxide anion radicals during the oxygen delignification of bamboo kraft pulp and the enhancing affect of anthraquinone compounds as an additive on delignification. The results indicated that the superoxide anion radicals could react with lignin and remove it from pulp with negligible damage on cellulose, and the anthraquinone-2-sulfonic acid sodium salt could facilitate the generation of superoxide anion radical to enhance delig- nification of pulps. The oxygen delignification selectivity could be improved using the 1,2,3-trihydroxybenzene auto-oxidation system combined with anthraquinone-2-sulfonic acid sodium salt.

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期刊信息
  • 《中国化学工程学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国化学工业与化学工程学会
  • 主编:
  • 地址:北京东城区青年湖路13号
  • 邮编:100011
  • 邮箱:cjche@cip.com.cn
  • 电话:010-64519487/88
  • 国际标准刊号:ISSN:1004-9541
  • 国内统一刊号:ISSN:11-3270/TQ
  • 邮发代号:
  • 获奖情况:
  • 1998年化工系统优秀信息成果一等奖,中国期刊方阵“双效”期刊
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  • 被引量:385