选用β—Si3N4粉体代替传统的SiO2填料与环氧树脂复合,制备新型高导热电子模塑料.初步研究了单独添加β—Si3N4及与SiO2复合添加对复合材料导热性能的影响.结果表明:β—Si3N4粉体可以显著提高复合材料的导热性能,当填充率达到50vol%时,β—Si3Na填充复合材料热导为SiO2填充复合材料的约3.8倍.并在实验基础上,探讨了复合材料的热导率计算模型,给出了单一填充和复合填充复合材料的Agari热导率计算模型表达式及相关参数.
New electric molding composites were fabricated with hybridizing epoxy andβ-Si3N4 instead of silica. The thermal conductivity of composites filled with β-Si3N4 was compared with that co-filled with β-Si3N4 and SiO2. The results demonstrate that the thermal conductivity of the composite increases obviously with the increasing of β-Si3N4 content. Thermal conductivity of β-Si3N4-filled composite is about 3.8 times as large as that of SiO2-filled one when the additional volume fraction achieves to 50%. Based on the experimental results, the discussion of calculating model for predicting thermal conductivity of composites shows that Agari model is more applicable to predict the thermal conductivities of β-Si3N4 filled and β-Si3N4/SiO2 co-filled composites. Furthermore, a common expression of Agari model for co-filled composites and its parameters are given.