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Measurements and thermodynamic modeling of liquid-liquid equilibria in ternary system 2-methoxy-2-methylpropane+ p-cresol + water
  • ISSN号:1004-9541
  • 期刊名称:《中国化学工程学报:英文版》
  • 时间:0
  • 分类:TQ013.1[化学工程] O642.42[理学—物理化学;理学—化学]
  • 作者机构:Key Laboratory of Heat Transfer Enhancement and Energy Conservation of Ministry of Education, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou510640, China
  • 相关基金:Supported by the Project of the Science & Technology New Star of Pearl River in Guangzhou (2011J2200056), the Fundamental Research Funds for the Central Universities, SCUT (2014ZZO057,2015ZM046), and the National Natural Science Foundation of China (20906028, 21506066).
中文摘要:

Liquid–liquid equilibrium(LLE)data for the ternary system 2-methoxy-2-methylpropane(methyl tert-butyl ether)+ p-cresol + water was measured at atmospheric pressure and temperatures of 298.15 K and 313.15 K.From the distribution coefficients and selectivity,it was found that 2-methoxy-2-methylpropane is an efficient solvent to extract p-cresol from wastewater.The consistency of the experimental tie-line data was verified with the Hand and Bachman equations.These data were also correlated with the non-random two liquid(NRTL)and universal quasi-chemical correlation activity coefficient(UNIQUAC)models to yield binary interaction parameters for p-cresol extraction process evaluation.Both models agreed with experiments very well,yet the NRTL model showed even smaller average deviation than the UNIQUAC model.

英文摘要:

Liquid-liquid equilibrium (LLE) data for the ternary system 2-methoxy-2-methylpropane (methyl tert-butyl ether) + p-cresol + water was measured at atmospheric pressure and temperatures of 298.15 K and 313.15 K. From the distribution coefficients and selectivity, it was found that 2-methoxy-2-methylpropane is an efficient solvent to extract p-cresol from wastewater. The consistency of the experimental tie-line data was verified with the Hand and Bachman equations. These data were also correlated with the non-random two liquid (NRTL) and universal quasi-chemical correlation activity coefficient (UN1QUAC) models to yield binary interac- tion parameters for p-cresol extraction process evaluation. Both models agreed with experiments very well, yet the NRTL model showed even smaller average deviation than the UNIQUAC model.

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期刊信息
  • 《中国化学工程学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国化学工业与化学工程学会
  • 主编:
  • 地址:北京东城区青年湖路13号
  • 邮编:100011
  • 邮箱:cjche@cip.com.cn
  • 电话:010-64519487/88
  • 国际标准刊号:ISSN:1004-9541
  • 国内统一刊号:ISSN:11-3270/TQ
  • 邮发代号:
  • 获奖情况:
  • 1998年化工系统优秀信息成果一等奖,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
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  • 被引量:385