中文摘要：

The model compounds of androgenic steroid-bismetallopor-phyrins 3a-3d and androgenic monometalloporphyrins 2a-2d have been synthesized. Catalytic study in two-phase condition on epoxidation of styrene under the catalysis of model catalysts shows (hat the catalytic performances of steriod-bismet-alloporphyrin is superior to steroid- metalloporphyrin and the corresponding simple metalloporphyrin. The excellent catalytic property of steriod-bismetallopotphyrin can be rationalized as the hydrophobic action of steroid framework and the cooperative action of two metalloporphyrins in catalysis.

英文摘要：

The model compounds of androgenic steroid-bismetalloporphyrins 3a—3d and androgenic monometalloporphyrins 2a—2d have been synthesized. Catalytic study in two-phase condition on epoxidation of styrene under the catalysis of model catalysts shows that the catalytic performances of steroid-bismetalloporphyrin is superior to steroid-metalloporphyrin and the corresponding simple metalloporphyrin. The excellent catalytic property of steriod-bismetalloporphyrin can be rationalized as the hydrophobic action of steroid framework and the cooperative action of two metalloporphyrins in catalysis.