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Oxidative Desulfurization of Model Sulfur Compound by Potassium Ferrate in the Presence of Phosphomolybdic Acid Catalyst
  • ISSN号:1008-6234
  • 期刊名称:《中国炼油与石油化工:英文版》
  • 时间:0
  • 分类:TQ131.13[化学工程—无机化工] TQ281[化学工程—有机化工]
  • 作者机构:[1]Provicial Key Laboratory of Oil and Gas Chemical Engineering, College of Chemistry and Chemical Engineering, Northeastern Petroleum University, Daqing 163318, [2]Daqing Petrochemical Engineering Co., Ltd., Daqing 163714
  • 相关基金:financially supported by the Science and Technology Program of the Department of Education,Heilongjiang Province(11531012)
中文摘要:

In this work, the removal of thiophene from simulated oil has been studied by using the adsorption, extraction and oxidation/adsorption methods, respectively. In the adsorptive desulfurization process, different commercial adsorbents were used to eliminate thiophene at ambient pressure and mild temperature, and the results showed that carbon powder had the best adsorption ability. In the extractive desulfurization process, the best desulfurization result was obtained when DMF is used. In the oxidative/adsorptive desulfurization procedure using synthesized potassium ferrate as the oxidant and phosphomolybdic acid solution as the catalyst, thiophene was oxidized and removed from hydrocarbons in combination with active carbon adsorption, and the residual sulfur content of simulated oil could be reduced to 15.3mg/L from the original level of 200mg/L, with the desulfurization rate reaching 92.3%.

英文摘要:

In this work, the removal of thiophene from simulated oil has been studied by using the adsorption, extraction and oxidation/adsorption methods, respectively. In the adsorptive desulfurization process, different commercial adsorbents were used to eliminate thiophene at ambient pressure and mild temperature, and the results showed that carbon powder had the best adsorption ability. In the extractive desulfurization process, the best desulfurization result was obtained when DMF is used. In the oxidative/adsorptive desulfurization procedure using synthesized potassium ferrate as the oxidant and phos- phomolybdic acid solution as the catalyst, thiophene was oxidized and removed from hydrocarbons in combination with ac- tive carbon adsorption, and the residual sulfur content of simulated oil could be reduced to 15.3 mg/L from the original level of 200 mg/L, with the desulfurization rate reaching 92.3%.

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期刊信息
  • 《中国炼油与石油化工:英文版》
  • 主管单位:中国石化集团公司
  • 主办单位:SINOPEC 石油加工研究所
  • 主编:汪燮卿
  • 地址:北京学院路18号
  • 邮编:100083
  • 邮箱:sylz@ripp-sinopec.com
  • 电话:010-82368292
  • 国际标准刊号:ISSN:1008-6234
  • 国内统一刊号:ISSN:11-4012/TE
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库)
  • 被引量:37