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铜含量对Al-Zn-Mg-Cu-Zr-Cr-Yb超强铝合金组织与性能的影响
  • ISSN号:1673-0224
  • 期刊名称:粉末冶金材料科学与工程
  • 时间:2014.10.20
  • 页码:23-26
  • 分类:TG146[金属学及工艺—金属材料;一般工业技术—材料科学与工程;金属学及工艺—金属学]
  • 作者机构:[1]中南大学粉末冶金国家重点实验室,长沙410083, [2]中南大学化学化工学院,长沙410083, [3]School of Chemical Engineering, Purdue University, West Lafayette 47907, IN, USA
  • 相关基金:Projects(51134007,51201186)supported by the National Natural Science Foundation of China; Project(51327902)supported by the Major Research Equipment Development,China; Projects(2012CB619502,2010CB731701)supported by the National Basic Research Program of China; Project(12JJ6040)supported by the Natural Science Foundation of Hunan Province,China
  • 相关项目:晶界结构和晶界析出相对Al-Zn-Mg-Cu合金断裂及腐蚀的影响
中文摘要:

对比研究一种新型三级时效制度(T76+T6)和常规回归再时效制度(RRA T77)对7150铝合金型材耐腐蚀性能的影响。选取三种腐蚀溶液(3.5%Na Cl;10 mmol/LNaCl+0.1 mol/L Na2SO4;4 mol/LNa Cl+0.5 mol/L KNO3+0.1mol/L HNO3),分别对7150铝合金型材进行开路电位、循环极化曲线以及电化学阻抗谱的表征。讨论自腐蚀电位、点蚀电位、点蚀转换电位以及电位差值等参数对铝合金腐蚀表征的适用性与局限性。电化学与扫描电镜(SEM)结果表明,相比于传统RRA T77制度,T76+T6时效制度处理的铝合金在没有强度损失的前提下,具备更好的耐点蚀、耐晶间腐蚀以及耐剥落腐蚀的能力。这是由于该新型三级时效制度处理的铝合金的晶界析出相进一步粗化和断续分布所致。

英文摘要:

The effects of a novel three-step aging process (T76+T6) on the electrochemical corrosion behavior of 7150 extruded aluminum alloy were evaluated and compared with those of the conventional retrogression and re-aging process (T77). The open circuit potential (OCP), cyclic polarization and electrochemical impedance spectra (EIS) of the A1 alloys were measured after treatment in three solutions (3.5% NaCl (mass fraction); 10 mmol/L NaCl + 0.1 mol/L Na2SO4; 4 mol/L NaCl + 0.5 mol/L KNO3 + 0.1 mol/L HNO3). The parameters including the corrosion potential, pitting potential, pit transition potential and steepness, and potential differences were extensively discussed to evaluate the corrosion behavior of the Al alloys. The electrochemical and scanning electron microscopy (SEM) data show that compared with the 7150-T77 Al alloy, the T76 + T6 aged 7150 A1 alloy exhibits better resistance to pitting corrosion, inter-granular corrosion (IGC) and exfoliation corrosion, which is attributed to further coarsening and inter-spacing of the grain boundary particles (GBPs) as revealed by transmission electron microscopy. Furthermore, the hardness tests indicate that an attractive combination of strength and corrosion resistance was obtained for the 7150 Al alloy with T76 + T6 treatment.

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期刊信息
  • 《粉末冶金材料科学与工程》
  • 北大核心期刊(2011版)
  • 主管单位:教育部
  • 主办单位:中南大学
  • 主编:黄伯云
  • 地址:长沙市麓山南路中南大学粉末冶金研究院
  • 邮编:410083
  • 邮箱:pmbjb@csu.edu.cn
  • 电话:0731-88877163
  • 国际标准刊号:ISSN:1673-0224
  • 国内统一刊号:ISSN:43-1448/TF
  • 邮发代号:42-321
  • 获奖情况:
  • 国内外数据库收录:
  • 荷兰文摘与引文数据库,美国工程索引,中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:3662