中文摘要：

为用在空基于按的多孔的器官的聚合物(H-CPPs ) 的非共有原子价相互作用的转变金属催化剂的 heterogenization 的一条灵巧的途径被介绍。催化地活跃的 cationic 种，[Ru (bpy )₃]²⁺(bpy = 2,2-bipyridyl ) ，经由静电的相互作用在 H-CPPs 被使不能调动。内在的性质[Ru (bpy )₃]²⁺ 很好被保留。当在可见光的照耀下面为 4-methoxyphenylboronic 酸的氧化 hydroxylation 使用了到 4-methoxyphenol 时，产生 Rucontaining 空聚合物展出了优秀催化活动，提高的稳定性，和好再循环能力。吸引人的催化表演主要从有效集体转移和 cationic Ru 建筑群的化学性质的维护导致了 H-CPPs。

英文摘要：

A facile approach for the heterogenization of transition metal catalysts using non-covalent interactions in hollow click-based porous organic polymers （H-CPPs） is presented. A catalytically active cationic species, [Ru（bpy）3]〉 （bpy = 2,2＇-bipyridyl）, was immobilized in H-CPPs via electrostatic interactions. The intrinsic properties of [Ru（bpy）3]〉 were well retained. The resulting Ru- containing hollow polymers exhibited excellent catalytic activity, enhanced stability, and good recyclability when used for the oxidative hydroxylation of 4-methoxyphenylboronic acid to 4-methoxyphenol under visible-light irradiation. The attractive catalytic performance mainly resulted from efficient mass transfer and the maintenance of the chemical properties of the cationic Ru complex in the H-CPPs.