中文摘要：

以四氯化锆、三氯乙烯及苯乙炔为原料，通过有机锂法合成锆炔杂化树脂（PZA），通过FT—IR、1H—NMR表征了其结构，利用FTIR、DSC及TGA研究了PZA树脂的固化反应及耐热性能；采用XRD研究了PzA树脂固化物的烧结性能。结果表明：PZA树脂可以发生固化交联反应；其固化物具有一定的耐热性能，在氮气气氛中，失重10％的温度（Td10）达到500℃，1000℃下的质量保留率达到80％；在空气气氛中，1000℃下烧结可形成四方氧化锆陶瓷。

英文摘要：

A new kind of zirconium-acetylene hybrid resin was synthesized from trichloroethylene, phenylacetylene and zirconium tetrachloride using organolithium method. The structures of resin were characterized by FT-IR and 1H-NMR. Thermal curing process was monitored by DSC and FT-IR. Thermal and oxidative properties were evaluated by TGA analysis. Results showed the PZA resin can cure. The cured PZA resins had good thermal stability, the temperature of 10% mass loss （Td10） under nitrogen was up to 500 ℃ and the residual at 1 000 ℃ was 80 %. α-ZrO2containing ceramic was obtained after sintering at 1 000 ℃.