引言 城市生活垃圾填埋场渗滤液(以下简称为“渗滤液”)中的污染物组成和浓度与填埋场的环境条件、填埋年限等因素密切相关。早期渗滤液含有高浓度较易降解的有机物和氨氮。晚期渗滤液中有机物浓度低而且可生化性差,但氨氮浓度有增无减。理论和实际运行结果表明,完成硝酸盐反硝化需要COD/TKN为4.0,但晚期渗滤液生物脱氮时反硝化的有机碳源不足。因而对于晚期渗滤液处理的重点和难点是:如何经济有效地去除高氨氮,同时在碳源缺乏的情况下,提高总氮去除率。
Both "two-stage upflow anaerobic sludge blanket (UASB) +anoxic/oxic (A/O)" system and "one stage UASB+A/O" system were successively introduced to treat a leachate containing relatively low concentration of organics and high concentration of ammonia from a mature landfill site. The "two-stage UASB+A/O" system was used firstly. The denitrification of the return effluent was carried out in the first stage UASB (UASB1) . The nitrification took place in the A/O reactor. The results showed that most biodegradable organic matter was removed in the UASB1, so "one stage UASB+A/O" system was used in the second phase experiment. The NH4^+-N loading rate of A/O reactor and operation temperature were 0.28-0.60 kg NH4^+-N · m^-3 · d^-1 and 17-29℃, respectively. The COD removal efficiency and the final effluent COD were 50%-70%, 1000-1500 mg ·L^-1, respectively. Short-cut nitrification with 90%- 99% of nitrite accumulation efficiency took place in the system. The NH4^+-N removal efficiency varied between 90% and 100%. When NH4^+-N loading rate was less than 0.45 kg NH4^+-N · m^-3 · d^-1 , the NH4^+- N removal efficiency was more than 98%, and effluent NH^+-N was below 15 mg · L^-1. When the ratio of the feed COD to feed NH4^+-N concentrations was 2-3, the total inorganic nitrogen (TIN) removal efficiency was 70%-80%. The sludge samples from A/O reactor were analyzed by using fluoresence in situ hybridization (FISH) . The FISH analysis showed that ammonia oxidation bacteria (AOB) were 4% of the eubacteria, meanwhile nitrite oxidation bacteria (NOB) were less than 0.2% of the eubacteria.