利用高温固相法制备了BaMoO4:Eu3+发光材料,采用X射线衍射(XRD)和荧光光谱仪对样品进行测试。结果表明,在800℃时得到BaMoO4纯相,属四方晶系。激发光谱由一个宽带和处在350 nm后的若干个线状谱组成,宽带归属于Eu3+—O2-电荷迁移吸收带(CT),线状谱属于Eu3+的f—f激发跃迁吸收。发射光谱由5D0—7F1(591 nm),5D0—7F2(615 nm),5D0—7F3(654 nm)和5D0—7F4(702 nm)四组峰组成,其红光5D0—7F2辐射跃迁发射最强,对应Eu3+的电偶极跃迁。
The BaMoO4∶Eu3+ phosphors were synthesized by solid-state method and were characterized by X-ray diffraction(XRD) and photoluminescence spectra.XRD analysis confirmed the formation of BaMoO4 at 800 ℃ and exhibited a tetragonal crystal structure.The excitation spectrum of samples showed one broad band and some peaks located behind 350 nm.The former was attributed to the charge transfer transition of Eu3+—O2-,while the latter belonged to the f—f transitions of Eu3+ ions.The emission spectrum shows four peaks at 591,615,654 and 702 nm,respectively.The dominant peak is located at 615 nm due to the 5D0—7F2 electric dipole transition of Eu3+.