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Nitrogen-rich 6-（3,5-Dimethylpyrazol-1-yl）-3-（2,4,6-trinitroanilino）-1,2,4,5-tetrazin： Synthesis, Crystal Structure and Thermal Property
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 时间：0
  • 分类：O626[理学—有机化学;理学—化学]
  • 作者机构：[1]State Key Labarotory of Explosion Science and Technology, Department of Chemistry, and Institute for Chemical Physics, Beijing Institute of Technology, Beijing 100081, China, [2]College of Chemistry, Chongqing Normal University, Chongqing 400047, China
  • 相关基金：Project supported by the National Natural Science Fund of China （Nos. 20671011, 20331010, 90406002 and 90406024）, the 111 Project （No. B07012） and Key Laboratory of Structural Chemistry Foundation （KLSCF, No. 060017）.
作者： 潘万龙[1], 黄坤林[2], 唐望[1], 许颜清[1], 胡长文[1]
关键词： 四嗪, 三硝基苯胺, 合成, 晶体结构, 热性能, tetrazine, trinitroaniline, synthesis, crystal structure, helix
中文摘要：

6-(3,5-Dimethylpyrazol-1-yl )-3-(2,4,6-trinitroanilino)-1,2,4,5-tetrazin (1 ) 被 1H NMR， MS，元素的分析，红外线的系列和热分析综合了并且描绘。水晶结构被 X 光检查衍射方法决定。1 在单斜晶的水晶系统的 P21/c 空格组被使结晶，并且展出好物理性质，例如高密度(> 在他们在与另外的酉分的污染物质之一或二共存的一个相当宽的范围的氧化山峰水流和他们的相应集中之间的 1.55 gship。察觉限制 o 吗？

英文摘要：

6-（3,5-Dimethylpyrazol-1-yl）-3-（2,4,6-trinitroanilino）-1,2,4,5-tetrazin （1） has been synthesized and characterized by ^1H NMR, MS, elemental analysis, infrared spectra and thermal analyses. The crystal structure was determined by X-ray diffraction method. 1 is crystallized in P21/c space group of monoclinic crystal system, and exhibits good physical properties, such as high densities （〉 1.55 g·cm^-3） and good thermal stabilities （Td〉220 ℃）. The intrermolecular hydrogen bonds construct the P- and M-helices from organic molecules and may contribute to the high melting points.

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期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175