中文摘要：

采用水热法合成了3种以5-氨基间苯二甲酸根为桥连配体的Co（Ⅱ）配聚物：[Co2（aip）2（bipy）]n.2nH2O（1）,[Co（aip）（imH）]n（2）和[Co（aip）（phen）]n（3）（H2aip=5-氨基间苯二甲酸,bipy=2,2＇-联吡啶,imH=咪唑,phen=1,10-邻菲啰啉）.通过X射线单晶衍射、红外（IR）光谱、紫外-可见（UV-Vis）吸收光谱、元素分析、表面光电压光谱（SPS）和场诱导表面光电压光谱（FISPS）等方法对配聚物进行了表征.结构解析表明,配聚物1具有3D无限结构,配聚物2和3具有2D无限结构,但它们又分别通过氢键或π-π堆积作用进一步形成3D无限结构.在配聚物中,aip基团采取了μ3-ηo1ηo1ηo1ηo2,μ5-ηn1ηo1ηo1ηo1ηo1,μ3-ηn1ηo1ηo1和μ3-ηn1ηo1ηo1ηo1 4种配位模式.SPS和FISPS结果显示,配聚物1～3在300～800 nm范围内均呈现正的表面光伏响应（SPV）,表明3个配聚物均具有一定的光电转换能力.讨论了配位环境和空间维度对配聚物表面光电响应的影响以及SPS与UV-Vis吸收光谱的对应关系.

英文摘要：

Three Co（Ⅱ） coordination polymers with the ligand of 5-aminosalicylic groups,[Co2（aip）2／5（bipy）]n·2nH2O（1）,[Co（aip）（imH）]n（2） and [Co（aip）（phen）]n（3）（H2aip=5-aminosalicylic acid,bipy=2,2＇-bipyridine,imH=imidazole,phen=1,10-phenanthroline） were synthesized by hydrothermal method.The structures were characterized by X-ray single crystal diffraction,IR spectrum,UV-Vis spectrum,elemental analysis,surface photovoltage spectroscopy（SPS） and field-induced surface photovoltage spectroscopy（FISPS）.The structural analyses indicate that complex 1 is 3D infinite coordination polymer;complexes 2 and 3 are both 2D infinite coordination polymers,and hydrogen bonds link the complexes further connect to 3D infinite structures.There are four coordination patterns of aip groups： μ3-ηo1ηo1ηo1ηo2,μ5-ηn1ηo1ηo1ηo1ηo1,μ3-ηn1ηo1ηo1 and μ3-ηn1ηo1ηo1ηo1.SPS and FISPS results reveal that complexes 1—3 exhibit positive surface photovoltage responses in the range of 300—800 nm,which indicates that the three polymers have certain photo-electric conversion properties.The influences of coordiantion enviroment and demensition for the SPS and the relationships between UV-Vis spectra and SPS were disscussed.