中文摘要：

在可见光催化下,联合廉价易得的有机染料曙红Y与容易制备的镍催化剂在室温条件下,高效绿色地实现了分子内的脱氢芳构化,此过程中只放出氢气无副产物,无需外在氧化剂,条件温和,产率高,对环境友好.此外,在其他条件相同的情况下,将绝氧条件下的放氢反应跟与有氧条件下的需氧氧化反应进行了对照,发现汉斯酯衍生物及1,4-二氢嘧啶衍生物在放氢条件下得到较高产率;而在需氧氧化条件下3,4-二氢噻吩衍生物、2,5-二氢吡咯衍生物芳构化的转化率更高.

英文摘要：

Pyridine derivatives play an important role in curing and controlling mites, bacteria, weed and so on. Pyrimidine derivatives exist in a number of bioactive natural products, and they have anti-allergy, anti-cancer, anti-inflammatory, insecticidal and some other properties. 3,4-Disubstituted thiophenes not only are important units for the synthesis of natural products, but also serve as key components in some biologically active compounds and material chemistry. In modern society, we have the urgent demand for achieving our products atom economicly and environment-friendly. Under this background, ＂atom-economy＂ reactions have been drawing great attention from many chemists and they have got many exciting improvements since then. So, we want to make our own contributions to this area and the following are some of our preliminary results. Our method was based on synergistic application of eosin Y with nickel（II） complex and an external oxidant-free oxidative dehydrogenation aromatization has been developed. At room temperature, Hantzsch 1,4-dihydropyridines, 1,4-dihydropyrimidines, 2,5-dihydrothiophenes and 2,5-dihydropyrroles were transformed into corresponding aromatic compounds in excellent yield under visible light irradiation via hydrogen evolution. We determined the hydrogen with GC-TCD using pure hydrogen as an external standard. It features very mild reaction conditions, high yields and excellent chemo-selectivity. In the previous reports, these transformations usually required higher temperatures and/or stronger oxidizing reagents, resulting in the generation of a large amount of by-products. In addition, the hydrogen evolution reactions were also compared with those of aerobic dehydrogenation. The results indicated that the dehydrogenation aromatizations of hantzsch 1,4-dihydropyridines and 1,4-dihydropyrimidine derivatives under the hydrogen evolution conditions proceeded in higher yields but very low conversions, while the reactions of 2,5-dihydrothiophenes and 2,5-dihydropyrroles gave higher co