以没食子酰基为功能基团,以改性纤维素为骨架合成功能高分子材料没食子酰化改性纤维素(没食子酰基-1,6-己二亚胺基-羟丙基-纤维素,CG):先将纤维素与环氧氯丙烷反应,然后依次接上己二胺桥链和三乙酰基没食子酰基,最后将没食子酰基脱去乙酰基得到目标产物。功能试验表明,1g产物能结合明胶49.5mg,并可再生使用。1g产物络合金属离子的能力:Fe^3+ 53.4mg,Cu^2+ 38.7mg,Hg^2+ 46.5mg,Mn^2+ 6.8mg,Zn^2+ 27.9mg,Pb^2+ 57.2mg。产物在稀酸、稀碱、稀醇和热水中具有稳定性。
A new type of functional polymer material, galloyl modified-cellulose (galloyl-1,6-hexyldiimino-oxypropyl-cellulose, CG ), was synthesized with phenolic acid as functional group and modified cellulose as molecular skeleton. The synthesis procedure was as follows: cellulose was first reacted with eplchlorohydrin, then the hexyl diamine bridge chain and triacetyl-galloyl group were successively connected, and finally the galloyl group was deacetylated. Functional tests indicated that 1 g of CG could adsorb 49.5 mg of gelatin and be reusable after regeneration, and complex the metallic ions such as: Fe^3+ 53.4 mg, Cu^2+ 38.7 mg, Hg^2+ 46.5 mg, Mn^2+ 6.8 nag, Zn^2+ 27.9 nag, Pb^2+ 57.2 nag, respectively. The product CG was stable in dilute acidic, alkaline, ethanolic solutions and hot water.