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Mechanism of cement-stabilized soil polluted by magnesium sulfate
  • ISSN号:2095-2899
  • 期刊名称:Journal of Central South University
  • 时间:2015.5.26
  • 页码:1869-1877
  • 分类:TQ132.2[化学工程—无机化工] U414.15[交通运输工程—道路与铁道工程]
  • 作者机构:[1]College of Architecture and Civil Engineering, Taiyuan University of Technology, Taiyuan 030024, China, [2]Department of Civil Engineering, The Penn State University, Harrisburg, PA 17057, USA
  • 相关基金:Projects(51208333,51078253)supported by the National Natural Science Foundation of China
  • 相关项目:污染土对钢铁材料的腐蚀影响与试验研究
中文摘要:

In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined compression strength(UCS) tests of blocks, X-ray diffraction(XRD) phase analysis of powder samples, microstructure by scanning electronic microscopy(SEM),element composition by energy dispersive spectrometry(EDS), and pore distribution analysis by Image Processed Plus 6.0(IPP 6.0)software. The UCS test results show that UCS of cemented soils reaches the peak value when the MS content is 4.5 g/kg. While, the UCS for Sample MS4 having the MS content of 18.0 g/kg is the lowest among all tested samples. Based on the EDS analysis results,Sample MS4 has the greater contents for the three elements, oxygen(O), magnesium(Mg) and sulfur(S), than Sample MS1. From the XRD phase analysis, C-A-S-H(3Ca O·Al2O3·3Ca SO4·32H2O and 3Ca O·Al2O3·Ca SO4·18H2O), M-A-H(Mg O·Al2O3·H2O), M-S-H(Mg O·Si O2·H2O), Mg(OH)2 and Ca SO4 phase diffraction peaks are obviously intense due to the chemical action associated with the MS. The pore distribution analysis shows that the hydrated products change the distribution of cemented soil pores and the pores with average diameter(AD) of 2-50 μm play a key role in terms of the whole structure of cemented soil. The microscopic structure of the cemented soil with MS exhibits the intertwined and embedded characteristics between the cement and granular soils from the SEM images of cemented soils. The microstructure analysis shows that the magnesium sulfate acts as the additive, which is beneficial to the soil strength when the MS content is low(i.e., Sample MS2). However, higher MS amount involving a chemical action makes samples crystallize and expand, which is adverse to the UCS of cemented soils(i.e., Sample MS4).

英文摘要:

In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined compression strength(UCS) tests of blocks, X-ray diffraction(XRD) phase analysis of powder samples, microstructure by scanning electronic microscopy(SEM),element composition by energy dispersive spectrometry(EDS), and pore distribution analysis by Image Processed Plus 6.0(IPP 6.0)software. The UCS test results show that UCS of cemented soils reaches the peak value when the MS content is 4.5 g/kg. While, the UCS for Sample MS4 having the MS content of 18.0 g/kg is the lowest among all tested samples. Based on the EDS analysis results,Sample MS4 has the greater contents for the three elements, oxygen(O), magnesium(Mg) and sulfur(S), than Sample MS1. From the XRD phase analysis, C-A-S-H(3Ca O·Al2O3·3Ca SO4·32H2O and 3Ca O·Al2O3·Ca SO4·18H2O), M-A-H(Mg O·Al2O3·H2O), M-S-H(Mg O·Si O2·H2O), Mg(OH)2 and Ca SO4 phase diffraction peaks are obviously intense due to the chemical action associated with the MS. The pore distribution analysis shows that the hydrated products change the distribution of cemented soil pores and the pores with average diameter(AD) of 2-50 μm play a key role in terms of the whole structure of cemented soil. The microscopic structure of the cemented soil with MS exhibits the intertwined and embedded characteristics between the cement and granular soils from the SEM images of cemented soils. The microstructure analysis shows that the magnesium sulfate acts as the additive, which is beneficial to the soil strength when the MS content is low(i.e., Sample MS2). However, higher MS amount involving a chemical action makes samples crystallize and expand, which is adverse to the UCS of cemented soils(i.e., Sample MS4).

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期刊信息
  • 《中南大学学报:英文版》
  • 主管单位:教育部
  • 主办单位:中南大学
  • 主编:黄伯云
  • 地址:湖南长沙中南大学校本部
  • 邮编:410083
  • 邮箱:jcsu@csu.edu.cn
  • 电话:0731-88836963
  • 国际标准刊号:ISSN:2095-2899
  • 国内统一刊号:ISSN:43-1516/TB
  • 邮发代号:42-316
  • 获奖情况:
  • 2006、2008、2010“中国高校精品科技期刊”2009...
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  • 被引量:334