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中国西北侏罗纪煤系显微组分热解油生物标志物特征及其意义
  • ISSN号:0379-1726
  • 期刊名称:《地球化学》
  • 时间:0
  • 分类:P593[天文地球—地球化学;天文地球—地质学]
  • 作者机构:[1]中国石油勘探开发研究院,北京100083, [2]中国石油天然气集团公司油气地球化学重点实验室,北京100083, [3]中国矿业大学煤炭资源教育部重点实验室,北京100083
  • 相关基金:国家自然科学基金(40373026)
中文摘要:

从西北地区侏罗纪煤中分离出来的不同显微组分热解油生物标志物总体上比较相似,但在一些特殊生物标志物的分布上存在明显差异。藻类体、孢子体、角质体热解油Pr/Ph比值一般在1.5-2.0之间,镜质体和基质镜质体热解油Pr/Ph比值在3~4之间,但均只有相应原煤抽提物Pr/Ph比值的一半。在常规生物标志物甾烷和萜烷组成中,藻类体和孢子体含有相对丰富的C27甾烷,角质体其次,镜质体和基质镜质体C27甾烷含量很低或者基本不含C27甾烷;藻类体和角质体含有较高的伽马蜡烷,而与藻类体来自相同原煤的孢子体伽马蜡烷含量很低;镜质体和基质镜质体基本上不含伽马蜡烷;分离显微组分的原煤伽马蜡烷含量均很低。由此可见,伽马蜡烷的含量不仅与有机质沉积水体的盐度有关,与母源的成分也有关系。显微组分热解油与煤系原油生物标志物组成特征对比表明,煤系原油是藻类体、孢子体、角质体等富氢组分和相对贫氢的镜质组生成产物的混合物。不同油气藏中的原油,每一类显微组分的贡献可能不尽相同,有些原油可能主要来源于藻类体和孢子体等富氢显微组分,而有些原油除了富氢显微组分有贡献外,镜质组对其也有一定的贡献,但富氢显微组分应该是煤系含油气盆地中主要的生油显微组分。

英文摘要:

Biomarkers in the pyrolysis oils produced by various macerals from Jurassic coals, the Northwest China are generally similar, with distinct differences in some special compounds. The oils generated by alginite, sporinite and cutinite have a lower Pr/Ph ratio range from 1.5 to 2.0, and the oils produced by vitrinite and desmocollinite have a higher value from 3 to 4, but Pr/Ph ratios of all pyrolysis oils are just a half of that of the extracts from the relevant raw coals. In the distribution of steranes and terpanes, the pyrolysis oils generated by alginite and sporinite contain relatively abundant C27 steranes, and cutinite, a little less. The pyrolysis oils produced by vitrinite and desmocollinite have extremely low C27 steranes, and even have no C27 steranes. The pyrolysis oils from alginite and cutinite show distinctly more gammacerane, and the Gammacerane/C31 hopanes (22S + 22R) ratio reaches 0.27, but the oil from sporinite isolated from the same coal with alginite contains little gammacerane. This indicates that the concentration of gammacerane is not only controlled by the salinity of depositional environment, but also concerned with the component of the contributing organic matter. The pyrolysis oils derived from vitrinite and desmocollinite demonstrate a very low concentration of gammacerane, with the Gammacerane/C31 hopanes (22S + 22R) ratio less than 0. 06. Biomarker correlation between the pyrolysis oils from various macerals and the crude oils from coal measures basins indicates that the crude oils in the coal-bearing basins are a mixture of the oils produced by hydrogen-rich macerals such as alginite, sporinite, cutinite, and by hydrogen-poor macerals such as vitrinite and desmocollinite. The contribution of each maceral to different crude oils varies. Some oils are probably derived from those of hydrogen-rich macerals, and Other oils may be partly derived from those of hydrogen-poor macerals, beside the hydrogen-rich macerals. Generally, the hydrogen-rich macerals are main organic matt

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期刊信息
  • 《地球化学》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院广州地球化学研究所 中国矿物岩石地球化学学会
  • 主编:傅家谟
  • 地址:广州市五山1131信箱
  • 邮编:510640
  • 邮箱:DQHX@GIG.AC.CN
  • 电话:020-85290046
  • 国际标准刊号:ISSN:0379-1726
  • 国内统一刊号:ISSN:44-1398/P
  • 邮发代号:2-813
  • 获奖情况:
  • 中国自然科学核心期刊,2000年中国科学院优秀期刊一等奖,百种中国杰出学术期刊,中国科协优秀期刊,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:18850