位置:成果数据库 > 期刊 > 期刊详情页
提高蛋白质生物塑料力学性能的研究进展
  • ISSN号:1000-6613
  • 期刊名称:《化工进展》
  • 时间:0
  • 分类:O636.1[理学—高分子化学;理学—化学] TB324[一般工业技术—材料科学与工程]
  • 作者机构:[1]西北工业大学材料学院,陕西西安710072, [2]仲恺农业工程学院绿色化工研究所,广东广州510225, [3]广州科技职业技术学院,广东广州510550
  • 相关基金:国家自然科学基金(20776164;21176269)及广东省自然科学基金(9251022501000003)项目.
中文摘要:

蛋白质生物塑料力学性能差是影响其商业化的主要因素。本文介绍了提高蛋白质生物塑料力学性能的几种手段,即蛋白质失活、生物纤维增强、与合成/天然可降解高分子共混、纳米复合增强等4个方面对提高其性能的有效性。对影响蛋白质失活的主要因素,即改变环境pH值、添加尿素、无机盐及交联剂等做了详细分析。对多种天然植物纤维的增强效果以及如何增强植物纤维在聚合物基体中的分散性、与其相容性等分别做了介绍。对多种纳米材料,如纳米纤维素、层状硅酸盐、碳纳米管/石墨烯等的增强效果也做了介绍。最后提出今后发展方向为:①提高蛋白质生物塑料的性能可控性,即兼顾可生物降解性与提高力学性能、延长使用寿命;②高性能化研究,以使蛋白质生物塑料满足某些特殊要求;③拓展蛋白质新来源。

英文摘要:

Protein-based bioplastics (PBBs), as a novel family of biodegradable plastics, have attracted increasing attentions thanks to their noticeable advantages in that they could be biodegraded completely and used by consumers in an environmentally friendly manner. However, PBBs are prone to be brittle under stress and their mechanical properties are inferior to their synthetic counterparts, which severely limits the commercialization of PBBs. Fortunately, numerous methods have been applied to overcoming these obstacles and have been found to be, in most cases, effective and successful. This paper summarizes four methodologies for improvement of mechanical properties of PBBs, namely protein denaturation, biofiber reinforcement, blends with synthetic/natural degradable polymers, and nanocomposites. Firstly, different factors influencing protein denaturation are analyzed, including pH value, addition of urea, inorganic salt, and cross-linking agents. Then, both the efficiency of mechanical properties improvement by incorporating natural plant fiber into protein matrix and the related fiber dispersion and compatibility between them are introduced. Next, the reinforcement efficiency of nano-sized fillers (nano whiskers/crystals, layered silicates, carbon nanotubes or grapheme) for mechanical enhancement is introduced. Finally, the future research trends are presented:① Controllable design of PBBs with combined and balanced properties such as biodegradable and mechanical properties, and the extension of service life; ② Value-added applications with desired functions, and ③ Exploring new protein resources.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《化工进展》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国化工学会 化学工业出版社
  • 主编:曹湘洪
  • 地址:北京市东城区青年湖南街13号
  • 邮编:100011
  • 邮箱:hgjz@263.net
  • 电话:010-64519500/9501/9502
  • 国际标准刊号:ISSN:1000-6613
  • 国内统一刊号:ISSN:11-1954/TQ
  • 邮发代号:82-311
  • 获奖情况:
  • 全国中文核心期刊,中国精品科技期刊,中国百种中国杰出学术期刊,第七届全国石油和化工行业优秀期刊一等奖,吕国化工学会会刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:37234