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Synthesis and characterization of wormhole-like mesoporous Ce0.6Zr0.35Y0.05O2 solid solutions
  • ISSN号:0023-074X
  • 期刊名称:《科学通报》
  • 时间:0
  • 分类:O614.332[理学—无机化学;理学—化学]
  • 作者机构:[1]Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemistry and Chemical Engineering, College of Environmentaland Energy Engineering, Beijing University of Technology, Beijing 100022, China
  • 相关基金:Supported by the National Natural Science Foundation of China (Grant No. 20473006) and PHR (IHLB). The authors thank Prof. C. T. Au of Hong Kong Baptist University for valuable suggestions.
中文摘要:

Ce_( 0.6 )Zr_( 0.35 )Y_( 0.05 ) O_2 ( CZY )固体的 Nanoparticles 答案被 CTAB ( hexadecyl-trimethyl 溴化铵)准备了,CTAB例如(乙二醇) templating ,并且 CTAB-EG-NaCl (在哪个先锋的毛孔综合了由CTAB例如,方法被 NaCl 的某个数量充满)方法分别地。这些材料的物理性质借助于象 X 光检查那样的技术被描绘衍射(XRD ) ,高分辨率扫描电子显微镜学(HRSEM ) ,传播电子显微镜学(TEM ) ,选择区域电子衍射(SAED ) ,和 N_2 adsorp-tion-desorption 大小。CZY 样品由上述三方法显示综合了像虫孔我酣睡的形态学和立方的晶体结构。Thematerials 在毛孔尺寸分发是狭窄的(平均毛孔直径 = 5.3—7.1 nm ) ,在表面区域高(95—119 m~2/g ) ,并且在毛孔体积大(0.16—0.18 cm~3/g ) 。NaCI 的介绍能够在高温度的锻烧保留 solidnanomaterials 的毛孔结构,这被表明了。

英文摘要:

Nanoparticles of Ce0.6Zr0.25Y0.05O2 (CZY) solid solution have been prepared by the CTAB (hexadecyltrimethyl ammonium bromide), CTAB-EG (ethylene glycol) templating, and CTAB-EG-NaCl (in which the pores of the precursor synthesized by the CTAB-EG method is filled by a certain amount of NaCl) method, respectively. The physical properties of these materials were characterized by means of tech- niques such as X-ray diffraction (XRD), high resolution scanning electron microscopy (HRSEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), and N2 adsorption-desorption measurements. The CZY samples synthesized by the above three methods display wormhole-like mesoporous morphology and cubic crystal structures. The materials are narrow in pore size distribution (averaged pore diameter = 5.3-7.1 nm), high in surface areas (95-119 m^2/g), and large in pore volumes (0.16-0.18 cm^3/g). It has been demonstrated that the introduction of NaCl is capable of retaining the pore structures of solid nanomaterials at high-temperature calcination.

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期刊信息
  • 《科学通报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院
  • 主编:周光召
  • 地址:北京东黄城根北街16号
  • 邮编:100717
  • 邮箱:csb@scichina.org
  • 电话:010-64036120 64012686
  • 国际标准刊号:ISSN:0023-074X
  • 国内统一刊号:ISSN:11-1784/N
  • 邮发代号:80-213
  • 获奖情况:
  • 首届国家期刊奖,中国期刊方阵“双高”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国数学评论(网络版),美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:81792