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东平湖可溶性有机物的荧光特征及环境意义
  • ISSN号:1673-4831
  • 期刊名称:《生态与农村环境学报》
  • 时间:0
  • 分类:X524[环境科学与工程—环境工程]
  • 作者机构:[1]聊城大学环境与规划学院,山东聊城252000, [2]中国科学院南京地理与湖泊研究所/湖泊与环境国家重点实验室,江苏南京210008, 3.国土资源部/广西岩溶动力学重点实验室,中国地质科学院岩溶地质研究所,广西桂林541004
  • 相关基金:国家自然科学基金(41301544,41401563);中国博士后科研基金(2015M571831);国土资源部/广西壮族自治区岩溶动力学重点实验室开放课题(KDL201506);山东省自然科学基金(ZR2012DQ003;ZR2013DL003)
中文摘要:

东平湖作为南水北调东线工程最后一级调水湖泊以及山东省西水东送的水源地,其水质状况对受水区的用水安全起决定性作用.基于2013年8月的东平湖采样,对各水质参数分析发现,东平湖目前仍处于中富-富营养化水平,水质总体接近GB3838-2002《地表水环境质量标准》IV类水质标准,仍不能满足调水要求,各水质参数表现出强烈的外源性.利用三维荧光光谱(EEMS)并结合平行因子分析法(PARAFAC)解析东平湖有色可溶性有机物的荧光特征,并探讨了荧光组分对东平湖环境污染指示意义的可行性.利用平行因子分析法(PARAFAC)共识别出2类4个荧光组分,分别是类腐殖质荧光组分C1(〈225/305,386nm)、C3(260,432nm)和类蛋白荧光组分C2(240,360nm)、C4(〈225/275,304nm).相关性分析发现,陆源类腐殖质荧光组分C1与间接反映有机污染程度的溶解性有机碳(DOC)和化学耗氧量(COD)具有显著相关性,类蛋白荧光组分C2与总氮具有显著正相关性,可以对东平湖富营养变化情况进行快速、长期的监测.

英文摘要:

The Dongping Lake holds a crucial position as the last water-staging lake of the east line of the Project of “ Diverting Water from South to North” of the country and the water source of the project diverting water from west to east in Shandong Province. Its water quality is directly related to water safety of the beneficiaries of the water diversion project. The water in the lake was sampled for analysis in August 2013 and all the water quality parameters indicate that the Lake was moderately or highly eutrophied and its water on the whole was close to Grade IV in quality set in the “Standard for Quality of Surface Water Environment” of the country and failed to meet the requirement of the water diversion project. All the water quality parameters show strong extraneousness. Fluorescent features of the chromophoric dissolved organic matters in the water were analyzed with EEMS and PARAFAC, and feasibility of using fluorescent components of the organic matters as indicators of environment pollution of the lake. PARAFAC analysis detected two classes and four types of fluorescent components, that is, C1 and C3 of the class of humic-like fluorescent components at 〈225/305,386 nm and 260,432 nm, respectively, and C2 and C4 of the class of protein-like fluorescent components at 240,360 nm and 〈225/275,304 nm, respectively. Terrigenous humic-like fluorescent component C1 was significantly related to DOC and COD, which may indirectly reflect degree of the organic pollution of the water, while protein-like fluorescent component C2 was significantly and positively related to TN. Therefore, the two components, C1 and C2 can be used as indicators for rapid determination and long-term monitoring of water eutrophication in the Dongping Lake.

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期刊信息
  • 《生态与农村环境学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国环境保护部
  • 主办单位:国家环境保护部南京环境科学研究所
  • 主编:蔡道基
  • 地址:江苏省南京市蒋王庙街8号
  • 邮编:210042
  • 邮箱:ere@vip.163.com
  • 电话:025-85287036
  • 国际标准刊号:ISSN:1673-4831
  • 国内统一刊号:ISSN:32-1766/X
  • 邮发代号:28-114
  • 获奖情况:
  • 全国优秀环境科技期刊,江苏省优秀期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),英国农业与生物科学研究中心文摘,荷兰地学数据库,荷兰文摘与引文数据库,美国生物科学数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:7943