中文摘要：

以1-羟乙基-3-甲基咪唑四氟硼酸（HEMIM[BF4]）和1-羟乙基-3-甲基咪唑双三氟甲磺酰亚胺（HEMIM-[N（SO2CF3）2]）离子液体为涂层材料,采用溶胶-凝胶方法制备了两种新型的离子液体-羟基硅油（OH-TSO）复合涂层固相微萃取探头,并对溶胶-凝胶反应机理和涂层性能进行了考察.由于阴离子结构不同,两种离子液体-OH-TSO复合涂层的性能也存在一定差异.首先,从表面形貌来看,HEMIM[BF4]-OH-TSO涂层表面孔洞排列更整齐,孔径更小,且大小均一.从热重分析结果来看,HEMIM[N（SO2CF3）2]-OH-TSO涂层具有更高的热稳定性,最高使用温度可以达到360℃.从萃取性能来看,HEMIM[BF4]-OH-TSO涂层对大多数酚类环境雌激素和芳胺的萃取效果明显高于HEMIM[N-（SO2CF3）2]-OH-TSO和未加离子液体的OH-TSO涂层.除此之外,它们还具有较强的抗溶剂冲洗能力,pH应用范围广,重现性好.以HEMIM[N（SO2CF3）2]-OH-TSO涂层为萃取头,采用固相微萃取-气相色谱法测定了实际水体中的芳胺.结果表明,该方法检测限低（6.3～201.3ng/L）,线性范围宽（3～4个数量级）,重现性好（RSD〈7%）,准确度高（回收率87.4%～111.5%）.

英文摘要：

Two hydroxylethyl-functionalized ionic liquids （ILs）,1-（2＇-hydroxylethyl）-3-methylimidazolium tetrafluoroborate （HEMIM[BF4]） and 1-（2＇-hydroxylethyl）-3-methylimidazolium bis-（trifluoromethanesul-fonyl）imide （HEMIM[N（SO2CF3）2]） were first used as selective stationary phase to prepare ILs-hy-droxyl-terminated silicone oil （OH-TSO） hybrid organic-inorganic coatings for solid-phase microextraction （SPME） by sol-gel technology. The underlying mechanism of the sol-gel reaction was proposed and the successful binding of ILs to the sol-gel substrate was confirmed by FT-IR spectra. The performance of these two ILs-based coatings was somewhat different,depending on the type of anions in ILs structure. Firstly,in contrast to HEMIM[N（SO2CF3）2]-OH-TSO coating,the pores on the surface of HEMIM[BF4]-OH-TSO coating are arranged more orderly and uniformly with a smaller size. Secondly,the HEMIM[N（SO2CF3）2]-based fibers had much higher thermal stability compared with the HEMIM[BF4]-based fibers. Thirdly,the extraction efficiency of HEMIM[BF4]-OH-TSO fiber towards phenolic environmental estrogens and aromatic amines was superior to that of HEMIM[N（SO2CF3）2]-OH-TSO fiber,and OH-TSO fiber without ILs. Moreover,these ILs-based SPME fibers had wonderful solvent resistance,wide useable pH range and good coating preparation reproducibility. Efficient analysis of aromatic amines with headspace SPME-GC was achieved using sol-gel-derived HEMIM[N（SO2CF3）2]-OH-TSO fiber. The method showed linear response over three to four orders of magnitude. The limits of detection were very low,ranged between 6.3 and 201.3 ng/L. The relative standard deviation values were below 7% and the recovery varied from 87.4% to 111.5%.