为研究典型有机污染物在南京地区的长距离输送潜力,以P,p'-DDT、7-HCH、BaP和HCB为研究对象,运用TaPL3模型计算了其在研究区大气及水体中的长距离输送潜力.结果表明,BaP和P,p’-DDT通过大气的特征迁移距离(CTD)较小,分别为198km和255km,表现为大气污染长距离输送能力较小,污染较难扩散;而y-HCH和HCB则更倾向于通过水体或大气进行长距离输送,其水体CTD分别为91558km和19056km,大气CTD分别为l858km和21104km,有利于其在研究区的扩散;水对y-HCH和HCB的黏着度为负值,分别为-2.1和-54.86,表明7-HCH和HCB更倾向于滞留在大气环境中,其通过大气并达到稳态后在大气中的质量分数为0.551%和2.2%;通过水体且达到稳态后在大气中的质量分数为0.149%和1.05%,高于P,P’-DDT和BaP.
In this study, the long-range transport potentials (LRTP) and HCB in air and water of Nanjing were estimated using the TaPL3 of typical organic pollutants including p,p'-DDT, T-HCH, BaP model. The research results showed that the characteristic travel distances (CTD) of BaP and p,p'-DDT through air were relatively low, 198 km and 255 km, respectively, indicating relatively low LRTP and difficulty in pollution dispersion. In contrast, y-HCH and HCB tended to transport over longer distances through water and air, with CTD values of 91 558 km and 19 056 km in water and 1 858 km and 21 104 km in air, respectively, indicating that the dispersion of pollution in air and water of the studied area was relatively easy. Furthermore, the stickiness of T-HCH and HCB in water was negative, and the values were -2. 1 and -54.86, respectively, indicating that T-HCH and HCB tended to remain in the atmosphere. The mass fractions in air after they passed air and achieved the steady state were 0. 551% and 2.2%, respectively, whereas the mass fractions in air after they passed water and achieved the steady state were 0. 149% and 1.05% , respectively, which were higher than those of p,p'-DDT and BaP.