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以CuCl纳米棒薄膜为前驱体制备CuS纳米/微米管和CuO纳米/微米晶薄膜
  • ISSN号：1007-4252
  • 期刊名称：《功能材料与器件学报》
  • 时间：0
  • 分类：TH7[机械工程—仪器科学与技术;机械工程—精密仪器及机械] TN4[电子电信—微电子学与固体电子学]
  • 作者机构：[1]吉林大学化学学院无机合成与制备化学国家重点实验室,长春130012, [2]吉林大学物理学院,长春130012
  • 相关基金：国家重点基础研究发展计划资助（No.2007CB613303）;国家自然科学基金资助（No.20501009;20331010）.
作者： 王群[1], 徐爽[2], 王科技[1], 张博[1], 李国栋[1]
关键词： 氯化亚铜, 硫化铜, 氧化铜, 薄膜, CuCl, CuS, CuO, thin film
中文摘要：

在本文中,以由氯化亚铜纳米棒组成的薄膜为前驱体,分别通过气-固相的硫化和氧化反应获得了由直径150到200纳米,长度达数微米的硫化铜管组成的薄膜和粒径为150到200纳米的氧化铜纳米/微米晶所组成的薄膜。利用XRD,SEM,TEM测试方法对薄膜的晶化度,纯度,形貌及结构特点进行了分析。制备的薄膜具有大尺寸,高比表面积,构筑单元为单晶的特点。研究表明,硫化铜纳米/微米管是通过克肯达尔效应形成的,而氧化铜纳米/微米晶是氯化亚铜与空气反应通过类似于化学气相沉积过程形成的。

英文摘要：

CuS thin film composed of nano/micro tubes with diameters in the range of 150 to 200 nm and lengths up to several microns and CuO thin film composed of nano/micro crystals with sizes ranging from 150 to 250 nm have been successfully prepared through using well - aligned CuCl nanorod films as precursor. features of the as - prepared films were studied by X a gas- solid sulfurization and oxidation reaction The crystallinity, purity, morphology and structural - ray diffraction （ XRD）, scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. The obtained films are large area, high aspect ratios and the building blocks are single - crystalline. Moreover, growth pathway of CuS nano/micro tubes can be described in terms of Kirkendall effect, while monoclinic CuO nano/micro crystals were pre-pared through the reaction of CuCl vapor species and O2/H2O in air, which is similar to the chemical vapor deposition （CVD） process.

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期刊信息
  • 《功能材料与器件学报》
  • 北大核心期刊（2011版）
  • 主管单位:中国科学院
  • 主办单位:中国材料研究学会 中国科学院上海微系统与信息技术研究所
  • 主编：邹世昌
  • 地址：上海市长宁路865号
  • 邮编：200050
  • 邮箱：jfmd@mail.sim.ac.cn
  • 电话：021-62511070
  • 国际标准刊号：ISSN：1007-4252
  • 国内统一刊号：ISSN：31-1708/TB
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  • 美国Ei,美国CA，英国SA，俄罗斯PЖ的文献源期刊,中国科技论文统计源期刊、中国科学引文数据库来源期刊,中国学术期刊综合评价数据库来源期刊
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  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）
  • 被引量:3051