采用高温固相反应法合成了掺杂Eu^3+及Tb^3+的17MO-7.88Y2O3-7582O3样品,研究了它们的光谱特性,结果表明,MO-Y2O3一B2O3基质在真空紫外(ⅥⅣ)区有很强的吸收,MgO-Y2O3-B2O3:Eu在147nm真空紫外光激发下产生对应于Eu^3+的^5D0→^7FJ(J=1,2,3,4)跃迁的59O和613nm强发射峰;MgO-Y2O3-B2O3:EuK中Sr的引入使材料体系在147nm附近的吸收和在613nm附近的发射获得明显增强;MgO-Y2O3-B2O3:Tb的真空紫外激发谱除在147nm附近的基质吸收外,还有对应于Tb^3+的4f^5d→4f^8跃迁位于170,178,195,204,225nm左右的一组谱峰,两者相互叠加使得材料在真空紫外区(120-220nm)内都有很好的吸收。
Eu and Tb doped 17MO-7.88Y2O3-75B2O3 samples were prepared by the solid state reaction. VUV excitation properties and 1 properties under VUV excitation were studied. Excitation spectra exhibited high absorption in VUV region (120-220 nm). There existed strong emission peaking at 591 and 613 nm corresponding to the ^5D0→^7FJ(J= 1, 2, 3, 4) emission transition of Eu^3+ when MO-Y2O3-B2O3:Eu was energized by the VUV radiation(147 nm). By the introduction of Sr into MO-Y2O3-B2O3 :Eu absorption peaking at 147 nm and red emission peaking at 613 nm are enhaneed strongly. Besides the host absorption band of MO-Y2O3-B2O3 :Tb, there existed strong absorption band peaking at 170, 178, 195, 204, 225 nm corresponding to the 4f^5→4f^7 5d transition of Tb^3+ ; emission spectra showed strong emission peaks at 491, 547, 590,621 nm corresponding to the ^5D0→^7FJ(J=6, 5, 4 and 3) emission transition of Tb^3+.