中文摘要：

在多孔管状莫来石支撑体外表面水热合成TS-1型分子筛膜．讨论了合成配比、合成温度、晶种引入等因素对膜合成的影响．采用X射线衍射仪（XRD）、红外光谱仪（FT-IR）、紫外可见分光光度计（UV-VIS）和扫描电子显微镜（SEM）对TS-1分子筛及分子筛膜进行了表征．通过乙醇-水混合物对膜的渗透汽化分离性能进行检测．结果表明，Ti进入了分子筛的骨架中，且最佳n（TiO2）／n（SiO2）=0．02，最佳合成温度200℃，采用原位法可以获得缺陷较少的TS-1分子筛膜．该膜对乙醇具有较好的选择性，分离因子为62，通量为0．76kg／（m^2·h）．

英文摘要：

TS-1 zeolite membranes were prepared hydrothermally on the outer-surface of porous mullite tubular supports. The effects of synthesis conditions, including composition, synthesis temperature, and seeds, were studied. The as-synthesized TS-1 zeolite and membranes were characterized by X-ray diffraction （XRD）, Fourier transform infrared spectrometry （FT-IR）, UV-Visible spectrophotometer （ UV-VIS）, and scaning electron microscope （SEM）. The membrane pervaporation separation properties for a feed ethanol-water mixture were tested. The results demonstrated that,Ti had come into framework of zeolite membranes, the better n （ TiO2 ）/n （ SiO2 ） was 0. 02, the better synthetic temperature was 200 ℃, and the membranes with less defects can be obtained by in-situ method. The zeolite membrane displayed good ethanol selectivity, and it had a separation factor of 62 with a flux of 0. 76 kg/（ m^2·h）.