采用高精度的流动型量热法测量了温度在303-396K、压力在0.1~0.5MPa时,质量摩尔浓度分别为0.648、3.700(无杂质)和3.700(含杂质)mol/kg三种配比硼酸溶液的比定压热容。实验系统的温度、压力、比定压热容的测量不确定度分别小于0.05K、18kPa、0.28%。为了验证实验系统的测量精度和可靠性,测量了温度为296~396K、压力为0.1~6.0MPa内纯水的比定压热容,与NIST值相比的相对偏差绝对平均值为0.41%。
Isobaric heat capacities of boric acid solution at the impurities) and 3. 700 mol/kg (containing impurities) were calorimeter at temperatures of 303-396 K and pressures of concentrations of 0. 648, 3. 700 (no measured using high accuracy flow 0.1-0.5 MPa. The uncertainties of temperature, pressure, and isobaric haet capacity were less than ±0.05 K, ±18 kPa and ± 0.28 %,respectively. In order to evaluate the reliability of the experimental system, pure water at temperatures of 296-396 K and pressures from atmosphere to and the measured average relative deviation from the NIST literature values isobaric 6.0 MP is withi heat capacities of a were measured, n 0. 41%.