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六水合硝酸镁增塑改性淀粉-聚乙烯醇复合膜的合成与性能
  • ISSN号:0251-0790
  • 期刊名称:高等学校化学学报
  • 时间:0
  • 页码:2822-2826
  • 分类:O636.12[理学—高分子化学;理学—化学]
  • 作者机构:[1]四川大学高分子研究所,高分子材料工程国家重点实验室,成都610065
  • 相关基金:基金项目:国家自然科学基金(批准号:50833003)资助.
  • 相关项目:聚乙烯醇基高分子材料制备和高性能化基本科学问题研究
中文摘要:

以六水合硝酸镁[Mg(NO3)2·6H2O]为增塑剂,采用流延法制备了增塑改性的淀粉-聚乙烯醇(PVA)复合膜,并研究了改性后淀粉-PVA复合膜的性能.研究结果表明,Mg(NO3)2·6H2O与淀粉和PVA发生一定的相互作用,破坏了淀粉和PVA中的结晶结构.因此,Mg(NO3)2·6H2O的加入可提高淀粉与PVA间的相容性,改变了淀粉-PVA复合膜的力学性能,使其拉伸强度下降,断裂伸长率提高.

英文摘要:

The plasticized starch/poly (vinyl alcohol) (PVA) film was prepared by casting method using magnesium nitrate hexahydrate [ Mg( NO3 )2· 6H2O] as the plasticizer. The micro morphologies of pure starch/ PVA and Mg (NO3 )2 · 6H2O plasticized starch/PVA film were observed by scanning electron microscope (SEM). The interaction between Mg( NO3)2 · 6H2O and starch/PVA molecule was investigated by Fourier transform infrared (FTIR). The crystallinity and thermal properties were measured by X-ray diffraction measurement(XRD) and thermogravimetric analysis (TGA). The mechanical properties were measured by tensile testing and dynamic mechanical analysis(DMA). It was found that Mg(NO3)2 · 6H2O could form some interaction with starch and PVA molecules. The addition of Mg( NO3 )2 · 6H2O could improve the miscibility of starch and PVA. The XRD results showed that Mg( NO3 )2 · 6H2O could destroy the crystals of starch and PVA. The TGA results showed that the thermal stability of starctCPVA decreased with the addition of Mg( NO3 )2 · 6H2O . Tensile testing showed that Mg( NO3 )· 6H2O was highly effective in modifying the mechanical properties of starch/PVA film, making the elongation at break of starch/PVA film largely increased from 8% of pure starch/PVA film to 514% with 60% Mg(NO3 )2 · 6H2O .

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编:周其凤
  • 地址:吉林大学南胡校区
  • 邮编:130012
  • 邮箱:cjcu@jlu.edu.cn
  • 电话:0431-88499216
  • 国际标准刊号:ISSN:0251-0790
  • 国内统一刊号:ISSN:22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:50676