以六水合硝酸镁[Mg(NO3)2·6H2O]为增塑剂,采用流延法制备了增塑改性的淀粉-聚乙烯醇(PVA)复合膜,并研究了改性后淀粉-PVA复合膜的性能.研究结果表明,Mg(NO3)2·6H2O与淀粉和PVA发生一定的相互作用,破坏了淀粉和PVA中的结晶结构.因此,Mg(NO3)2·6H2O的加入可提高淀粉与PVA间的相容性,改变了淀粉-PVA复合膜的力学性能,使其拉伸强度下降,断裂伸长率提高.
The plasticized starch/poly (vinyl alcohol) (PVA) film was prepared by casting method using magnesium nitrate hexahydrate [ Mg( NO3 )2· 6H2O] as the plasticizer. The micro morphologies of pure starch/ PVA and Mg (NO3 )2 · 6H2O plasticized starch/PVA film were observed by scanning electron microscope (SEM). The interaction between Mg( NO3)2 · 6H2O and starch/PVA molecule was investigated by Fourier transform infrared (FTIR). The crystallinity and thermal properties were measured by X-ray diffraction measurement(XRD) and thermogravimetric analysis (TGA). The mechanical properties were measured by tensile testing and dynamic mechanical analysis(DMA). It was found that Mg(NO3)2 · 6H2O could form some interaction with starch and PVA molecules. The addition of Mg( NO3 )2 · 6H2O could improve the miscibility of starch and PVA. The XRD results showed that Mg( NO3 )2 · 6H2O could destroy the crystals of starch and PVA. The TGA results showed that the thermal stability of starctCPVA decreased with the addition of Mg( NO3 )2 · 6H2O . Tensile testing showed that Mg( NO3 )· 6H2O was highly effective in modifying the mechanical properties of starch/PVA film, making the elongation at break of starch/PVA film largely increased from 8% of pure starch/PVA film to 514% with 60% Mg(NO3 )2 · 6H2O .