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Lead Determination on MWNT/Nafion Composite Modified Glassy Carbon Electrodes
  • ISSN号:1001-604X
  • 期刊名称:《中国化学:英文版》
  • 分类:O646[理学—物理化学;理学—化学]
  • 作者机构:[1]Key Labororatory of Analytical Chemistry for Life Science, Department of Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China
  • 相关基金:Project supported by the National Natural Science Foundation'of China (Nos. 20325516 and 90206037) and the Foundation of State Key Laboratory of Electroanalytical Chemistry from Changchun Institute of Applied Chemistry.
中文摘要:

硝酸的合成材料氧化了 multiwalled 碳 nanotube (MWNT ) 和 Nafion 被准备。如此的合成在一个玻璃质的碳电极上被修改由微分搏动的 voltammetry 决定铅的踪迹。在 pH=6.47 NaNO3 答案, Pb2+ 离子在修改电极上被积累在 ? 0.4 V。与相比一赤裸并且一部 Nafion 电影涂的电极,合成涂的 GC 电极能减少积累的潜力并且消除水银的有毒的特性。刻度情节在 5.0 桳潩的低集中是线性的吗?

英文摘要:

A composite material of nitric acid oxidized multiwalled carbon nanotube (MWNT) and Nation was prepared. Such composite was modified on a glassy carbon electrode to determine trace of lead by differential pulsed voltammetry. In pH=6.47 NaNO3 solution, Pb^2+ ions were accumulated on the modified electrode at -0.4 V. Compared with a bare and a Nation film coated electrode, the composite coated GC electrode can reduce the accumulating potential and eliminate the toxic character of mercury. The calibration plots were linear at low concentration of 5.0× 10^-9-2.0× 10^-8 mol/L and high concentration of 2.5× 10^-8-5.0× 10^-6 mol/L. The performances characteristics indicate that the electrode can be used to determine trace Pb^2+ ions.

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期刊信息
  • 《中国化学:英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编:
  • 地址:上海市枫林路354号中科院上海有机化学研究所
  • 邮编:200032
  • 邮箱:
  • 电话:021-54925243
  • 国际标准刊号:ISSN:1001-604X
  • 国内统一刊号:ISSN:31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175