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Quasi-solid state synthesis of EU-1 zeolite and its catalytic properties for the isomerization of C_8 aromatics
  • ISSN号:1001-3555
  • 期刊名称:《分子催化》
  • 时间:0
  • 分类:TQ221.213[化学工程—有机化工] O643.36[理学—物理化学;理学—化学]
  • 作者机构:[1]Chemical Engineering Department, Taiyuan University of Technology, Taiyuan, Shanxi 030024, China, [2]Petrochemical Research Institute, CNPC, Beijing 100083, China, [3]New Energy Research Institute, CNOOC New Energy Investment Co., Ltd., Beijing 100016, China, [4]China University of Petroleum, Beijing 102249, China
  • 相关基金:Acknowledgements This work was financially supported by the National Natural Science Foundation of China (No. 20973123) and thc National Basic Research Program of China (Grant No.2012CB215002).
中文摘要:

在这研究, EU-1 沸石成功地经由一条伪固体状态途径被综合并且为 C8 aromatics 异构化过程集合了到催化剂。催化性质通过 EU-1 沸石的酸味的小心的修正被调节并且催化剂做金属。EU-1 由于它的唯一的结构是 C8 aromatics 异构化过程的一个优秀候选人,这被显示出。另外,冒热气在 450500 点的 EU-1 的处理 ????????????? 贝吗??

英文摘要:

In this study,EU-1 zeolite was successfully synthesized via a quasi-solid state approach and assembled to catalyst for the C 8 aromatics isomerization process.The catalytic properties were tuned through careful modification of the acidity of EU-1 zeolites and metal-doping of the catalyst.It was shown that EU-1 was an excellent candidate for the C 8 aromatics isomerization process due to its unique structure.In addition,steam treatment of EU-1 at 450-500 ℃ could optimize the acidic properties of the catalyst,hence enhance its catalytic performance.The effect of the amount of Pt on ethylbenzene conversion was studied and the optimum amount was determined to be about 0.3-0.4 wt%.It was confirmed that EU-1 zeolite prepared via a quasi-solid state approach and then dealuminated by steam treatment had better activity and selectivity than conventional mordenite(MOR) zeolite and could be an excellent candidate for C 8 aromatics isomerization.

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期刊信息
  • 《分子催化》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院兰州化学物理研究所
  • 主编:李树本
  • 地址:兰州市天水路18号
  • 邮编:730000
  • 邮箱:fzch@licp.cas.cn
  • 电话:0931-4968226
  • 国际标准刊号:ISSN:1001-3555
  • 国内统一刊号:ISSN:62-1039/O6
  • 邮发代号:54-69
  • 获奖情况:
  • 1992年获中国科学院优秀期刊三等奖,1992年获甘肃省第二届优秀科技期刊荣誉称号
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:7932