用有机荧光染料罗丹明B(Rhodamine B)作为掺杂剂,采用双量子阱结构制备了一种新型的黄光有机电致发光器件,器件结构及各层厚度为:ITO/CuPc(6nm)/NPB(20nm)/Alq3(3nm)/Alq3:Rhodamine B(3nm)/Alq3(3nm)/Alq3:Rhodamine B(3nm)/Alq3(30nm)/Liq(5nm)/Al(30nm)。研究发现Rhodamine B的掺杂浓度对该器件的发光亮度和发光效率有较大影响。当Rhodamine B的掺杂浓度为1.5wt%时,得到了最大电流效率1.526cd·A^-1,最大发光亮度1309cd·m^-2的黄光有机电致发光器件。由器件的电致光谱曲线,可以看到在发光层之间存在着Alq3向RhB传递能量的过程。由于量子阱的斯托克斯效应与RhB染料分子间的自极化作用,随着掺杂浓度的增加,λmax出现明显红移。
The fabrication of a novel organic yellow-light-emitting device using Rhodamine B as dopant with double quantum-well (DQW) structure was introduced in the present article. The structure and thickness of this device is ITO/CuPc(6 nm)/NPB(20 nm)/Alq3 (3 nm)/Alq3 : Rhodamine B(3 nm) /Alq3 (3 nm)/Alq3 : Rhodamine B(3 nm)/Alq3 (30 nm)/Liq(5 nm)/Al(30 nm). With the detailed investigation of electroluminescence of the novel organic yellow-light-emitting device, the authors found that the doping concentration of Rhodamine B(RhB) had a very big influence on luminance and efficiency of the organic yellow-light- emitting device. When doping concentration of Rhodamine B (RhB) was 1.5 wt%, the organic yellow-light-emitting device was obtained with the maximum current efficiency of 1. 526 cd· A^-1 and the maximum luminance of 1 309 cd · m^-2. It can be seen from the EL spectra of the devices that there existed energy transferring from Alq3 to RhB in the organic light-emitting layers. When the doping concentration of RhB increased, λmax of EL spectra redshifted obviously. The phenomenon was attributed to the Stokes effect of quanturn wells and self-polarization of RhB dye molecules.