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CO2对X70钢在近中性pH值溶液中硫酸盐还原菌腐蚀行为的影响
  • ISSN号:1002-6495
  • 期刊名称:《腐蚀科学与防护技术》
  • 时间:0
  • 分类:TG172[金属学及工艺—金属表面处理;金属学及工艺—金属学]
  • 作者机构:辽宁石油化工大学石油天然气工程学院,抚顺113000
  • 相关基金:国家自然科学基金(51201009); 辽宁省自然科学基金(2013020078)
中文摘要:

对不同CO2浓度下硫酸盐还原菌(SRB)在近中性pH值(NS4)溶液的生长曲线,以及SRB生长周期对溶液pH值和电导率的影响进行了研究。采用极化曲线、电化学阻抗技术和扫描电镜(SEM)研究了CO2浓度对X70钢在有菌的NS4溶液中的腐蚀行为。结果表明:CO2在SRB代谢过程中起到了迟效碳源的作用,使SRB繁殖出现二次生长。SRB新陈代谢消耗了有机碳并释放出无机离子使溶液电导率在SRB对数生长期增加。SRB二次生长期消耗无机碳源(CO2)和化合物时并不产生新的离子导致溶液电导率下降。SRB生长周期对溶液pH值没有影响,pH值随时间和CO2浓度增加而略有增加。X70钢在有菌溶液中表面膜层表现出圈状裂纹,随CO2浓度增加,X70钢在NS4菌液中表面膜层致密性变差。CO2促进了金属表面点蚀的发展。

英文摘要:

The growth curve of sulfate reducing bacterial(SRB) in the near-neutral pH solution(NS4), and the effect of SRB growth cycle on the pH value and the conductivity of the solution were investigated. Then the corrosion behavior of X70 steel in CO2 containing NS4 solutions with SRB was studied by means of electrochemical impedance spectroscopy(EIS) and electro scanning microscope(SEM).The results showed that CO2 played a role as a slowly available carbon source to maintain the growth and metabolism process of SRB, which resulted in a secondary growth phase of SRB. The organic carbon was consumed by SRB metabolism, and thereby the inorganic ions were released at the same time,which resulted in the increase of solution conductivity in the logarithmic phase of SRB growth. CO2 was consumed as the inorganic carbon source in the secondary growth phase,while the inorganic ions were not emerged in the case, so the solution conductivity decreased. The growth cycle had little influence on p H value of the solution, which increased slightly with the increasing CO2 concentration and time. There were circle-shaped cracks on the X70 steel surface in the bacterial solution. With the increasing CO2 concentration in the bacterial solution, the compactness of the oxide scales formed on X70 steel surface gradually became worse, while pitting corrosion on the steel was promoted.

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期刊信息
  • 《腐蚀科学与防护技术》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院金属研究所
  • 主编:王福会
  • 地址:沈阳市文化路72号中国科学院金属研究所
  • 邮编:110016
  • 邮箱:cspt@imr.ac.cn
  • 电话:024-23971819
  • 国际标准刊号:ISSN:1002-6495
  • 国内统一刊号:ISSN:21-1264/TQ
  • 邮发代号:
  • 获奖情况:
  • 中国自然科学核心期刊,中国科技论文统计用刊,入编中国科学引文索引
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国剑桥科学文摘,英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:9973