欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
用循环伏安法（CV）和电化学扫描隧道显微镜（ECSTM）在HClO4溶液中研究了配对碱基腺嘌呤（Adenine,A）与胸腺嘧啶（Thymine,T）在Au（111）电极上的共吸附行为。CV曲线表明,A和T的电化学共吸附行为更接近于A的电化学吸附行为。高分辨STM图像显示,在物理吸附区域碱基A和T分子之间通过氢键作用形成一种不同于单组分的网络结构。根据STM图像提出一个可能的模型,并给出了在Au（111）电极上共吸附时A和T分子之间可能的氢键作用方式。
英文摘要：
The coadsorption behavior of two complementary DNA bases, adenine （A） and thymine （ T）, was studied on Au （ 111 ） electrode by cyclic vohammetry （CV） and electrochemical scanning tunneling microscopy （ECSTM） in aqueous solution. From the CVs, the coadsorption behavior of A and T was more closed to the adsorption behavior of A. In the potential range of physisorption, high- resolution ECSTM images of revealed that a new super-structure was formed by the hydrogen bonds between A and T. A molecular model of the super-structure was proposed based on the STM results and the possible hydrogen bonds between A and T.
同期刊论文项目
同项目期刊论文
Molecular recognition force spectroscopy of a specific lectin-carbohydrate interaction at single-mol
Bioassembled Nanocircuits of Mo6S9-xIx Nanowires for Electrochemical Immunodetection of Estrone Hapt
Electrochemistry of a C84-C2(IV)-Modified Electrode in Aqueous Solutions and Its Interaction with Gu
Study on the Electrochemistry of a Na(3)[Ti(2)P(2)O(10)F]center dot xH(2)O-Modified Glassy Carbon El
Study of Heterogeneous Electron Transfer on the Graphene/Self-Assembled Mono layer Modified Gold Ele
Highly sensitive detection of melamine and its derivatives by capillary electrophoresis coupled with
Atomic Force Microscopy Study on Chlorpromazine-Induced Morphological Changes of Living HeLa Cells I
Anion Transfer at a Micro-Water/1,2-Dichloroethane Interface Facilitated by beta-Octafluoro-meso-oct
Nanoscale Patterning of Multicomponent Proteins by Bias-Assisted Atomic Force Microscopy Nanolithogr
Investigation of the interactions between silver nanoparticles and Hela cells by scanning electroche
Kinetics of Heterogeneous Electron Transfer Reactions at the Externally Polarized Water/o-Nitropheny
The adsorption of dopamine on gold and its interactions with iron(III) ions studied by microcantilev
位置：