中文摘要：

以Ca3（PO3）2、滑石、石英及硼熔块为基本组成,采用四角配料法制备了R2O–RO–Al2O3–SiO2–P2O5–B2O3体系多相乳浊釉。通过X射线衍射及扫描电镜分析,研究了不同B2O3与P2O5的质量比和烧成温度对釉面性能及釉的显微结构等的影响,并对磷硼多相乳浊釉的乳浊机理进行了分析。结果表明：在磷酸钙的质量含量为3%～15%,B2O3与P2O5的质量比为1/2～2区域,在1200℃烧成可以得到白度较高的乳浊釉;B2O3/P2O5质量比不同时,釉熔体产生多次不混溶相,出现微相功能转换,乳浊度也随之改变;B2O3与P2O5的质量比为1时,因微相转换,釉中分相小滴相对较多,尺寸与可见光相近,且分散性高,使釉对光的折射与散射能力强,釉面呈现高乳白效果,白度可达87。

英文摘要：

The multiphase opalescent glaze was investigated in R2O–RO–Al2O3–SiO2–P2O5–B2O3 system with Ca3（PO3）2, talc, quartz and B2O3 frit as raw materials. The effects of the composition, B2O3 to P2O5 mass ratio and sintering temperature on the capability and macrostructure of the glaze were studied by scanning electron microscopy, and X-ray diffraction. The opacifying mechanism of phosphor-boron multiphase opalescent glaze was also analyzed. The results indicate that the ultra-white opalescent glaze can obtained when B2O3 to P2O5 mass ratio is in the region of 1/2–2, Ca3（PO3）2 mass fraction is at 3%–15%, and the sintering temperature is 1 200 ℃. Moreover, the opacification of the glaze would change with multiphase system and the transition of the microphase function due to the different B2O3 to P2O5 mass ratios. When the B2O3 to P2O5 mass ratio is 1, the whiteness of the glaze can be improved （The whiteness reached 87） with the increase of the high dispersion phase particles and droplets, which size is close to the wavelength of the visible light. The whiteness is also increased by phase separations in the glass phase and the transition of microphased function since the refraction and the scattering of the glaze have been improved.