钠离子电池具有钠资源丰富和成本低廉等特点,吸引了国内外研究者的广泛关注,被认为是今后在规模储能领域可能替代锂离子电池的最佳候选。近几年钠离子电池的研究相继取得了重要进展,研究体系不断丰富。本文对钠离子电池负极材料的研究现状进行了详细的综述,重点介绍了碳基材料、合金材料、非金属单质、金属氧化物以及有机化合物等嵌钠性能及可能的嵌钠机理。探讨了这些材料目前所面临的主要问题及可能的解决策略,并对钠离子电池今后的研究方向和应用前景进行了展望。
Room-temperature rechargeable Na ions batteries have attracted enormous interest due to its low cost and the environmental abundance of the sodium, which are considered as the best candidate for replacing the Li ion batteries in the large-scale electric energy storage. In recent years, the studies of Na ion batteries have made significant progress and the related components have been enriched. The current researches of anode materials for sodium ion batteries are reviewed in details, with emphasis on the electrochemical properties and charge- discharge mechanisms of carbon-based materials, alloys, non-metal substances, metal oxides and organic compounds. The main problems of these kinds of anode materials are discussed and the probable strategies are proposed. Then, the application prospective and the research directions of Na ions batteries in the future are also forecasted.