欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
以葡萄糖为碳源,由金属框架有机物（MOF）高效地合成出一种具有三维层次孔结构的多孔炭。当葡萄糖渗入到方形MOF的表面或内部空隙之后,逐步进行聚合和炭化。在此过程中,MOF分解出ZnO,ZnO进一步被基体炭或CO还原成Zn;而Zn又在炭化过程中逸出,以致形成连续的基体炭组织。当所合成的多孔炭用作双电层电容器电极材料时,在1 mol/L NEt4BF4/碳酸丙烯酯电解液体系中,其初始比电容达175 F.g-1（电流强度0.6 A.g-1）,并在12A.g-1大电流密度下电容保持率高达94.2%。
英文摘要：
A green and efficient method is presented to synthesize 3D hierarchical porous carbon from a metal organic framework（MOF） formed by 1,4-benzenedicarboxylic acid and zinc nitrate hexahydrate using glucose as the carbon precursor.Glucose was infiltrated into the external surface and/or voids of the cubic MOF,then polymerized and carbonized to form porous carbon.In the meantime,MOF was decomposed into ZnO,which was further reduced by carbon（or CO） into Zn that evaporated during carbonization.The morphology and pore characteristics of the products can be adjusted by changing the reaction time.When the synthesized porous carbon was used as the electrode material for electric double layer capacitors,it exhibited a high initial specific capacitance of 175 F · g-1 at 0.6 A · g-1 and a high capacitance retention of 94.2% at 12 A · g-1 in 1 mol/L NEt4BF4/propylene carbonate electrolyte.
同期刊论文项目
同项目期刊论文
The superior electrochemical performance of oxygen-rich activated carbons prepared from bituminous c
Molecular design of polymer precursors for controlling microstructure of organic and carbon aerogels
Effect of template and precursor chemistry on pore architectures of triblock copolymer-templated mes
Modification of polystyrene-based activated carbon spheres to improve adsorption of dibenzothiophene
Influence of nitrogen hetero-substitution on the electrochemical performance of coal-based activated
Fabrication of hierarchical porous carbide-derived carbons by chlorination of mesoporous titanium ca
Hollow carbon spheres with encapsulation of Co3O4 nanoparticles as anode material for lithium ion ba
LiFePO4/C nanocomposites synthesized from Fe2O3 by a hydrothermal reaction-calcination process and t
Structure control of V2O5/CNFs/cordierite monolith catalyst and its catalytic performance on NO remo
MnOx-CeO2/activated carbon honeycomb catalyst for selective catalytic reduction of NO with NH3 at lo
A high strength carbon nanofiber/honeycomb cordierite composite produced by chemical vapor depositio
Low-Temperature Selective Catalytic Reduction of NO with Urea Supported on Pitch-Based Spherical Act
Kinetics and Mechanism Study of Low-Temperature Selective Catalytic Reduction of NO with Urea Suppor
Asymmetric capacitance response from the chemical characteristics of activated carbons in KOH electr
Capacitive matching of pore size and ion size in the negative and positive electrodes for supercapac
New concept of in situ carbide-derived carbon/xerogel nanocomposite materials for electrochemical ca
Facile synthesis of hierarchically structured Fe(3)O(4)/carbon micro-flowers and their application t
Ion Transport Behavior in Triblock Copolymer-Templated Ordered Mesoporous Carbons with Different Por
Genetic algorithm-least squares support vector regression based predicting and optimizing model on c
Preparation of Highly- Conductive CNTs/Polyaniline Composites through Plasma Pretreating and In-situ
Hollow carbon nanospheres prepared by carbonizing polymethylmethacrylate/polyacrylonitrile core/shel
Surface modification of pitch-based spherical activated carbon by CVD of NH3 to improve its adsorpti
Preparation and microstructure control of carbon aerogels produced using m-cresol mediated sol-gel p
期刊信息
位置：