用化学络合的方法制得含弱荧光稀土离子错Pr(Ⅲ)和铒Er(Ⅲ)的单体,并经自由基聚合方法制得含Pr(Ⅲ)Er(Ⅲ)的聚丙烯酸酯聚合物。通过对聚合物薄膜的荧光分析发现,敏化离子La(Ⅲ)、Y(Ⅲ)、Yb(Ⅲ)的引入,使含弱荧光稀土离子镨Pr(Ⅲ)和铒Er(Ⅲ)的聚丙烯酸酯表现出了明显的荧光发射特性,且通过引入这些敏化离子,可实现对上述聚合物的特征荧光发射光谱的调控作用;同时发现敏化离子Yb(Ⅲ)对上述两种聚合物的荧光调控作用都较为明显。
The rare-earth-containing monomers were synthesized, and Pr( Ⅲ )-and Er( Ⅲ )-containing polyacrylates were obtained through free-radical copolymerizatioru The tunability of the fluorescence properties of the rare-earth-containing polyacrylates were achieved via incorporation of La( Ⅲ ), Yb( Ⅲ ) and Y( Ⅲ ) into the polymer systems. In particular, Yb(Ⅲ) showed greater fluorescence enhancement for the polymers compared with La(Ⅲ) and Y(Ⅲ). This study could offer a method for preparing fluorescent polymer systems with tunable fluorescence properties.