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石油醚-甲醇提取茶油和茶皂素工艺研究
  • ISSN号:1674-9669
  • 期刊名称:《有色金属科学与工程》
  • 时间:0
  • 分类:TS225.1[轻工技术与工程—粮食、油脂及植物蛋白工程;轻工技术与工程—食品科学与工程]
  • 作者机构:江西理工大学冶金与化学工程学院,江西赣州341000
  • 相关基金:国家自然科学基金资助项目(51364014);江西省科技厅资助项目(2013BBG70003);国家级大学生创新创业训练计划项目(201510407004);2014年度江西省普通本科高等学校专业综合改革试点项目(赣教高字(2014)43号)
中文摘要:

采用石油醚-甲醇为两相混合溶剂同时提取油茶籽枯饼中的茶油和茶皂素并探讨混合溶剂萃取茶油机理.分析甲醇浓度、混合溶剂用量,烃醇质量比,萃取温度、萃取时间对萃取效果的影响,确定较为合适的工艺参数为:甲醇浓度90%,固液质量比1∶3,烃醇质量比1∶1,萃取温度50℃,萃取时间90 min,萃取2次,粗茶油得率为8.42%,茶皂素得率为7.01%.实验提取的粗茶油颜色呈黄色稍带褐色,凝固点-2℃,酸值6.489 mg(KOH)/g,皂化值199.821 mg(KOH)/g,碘值78.616 g/(100g),粗茶油中不饱和脂肪酸含量高达85.006%,粗茶油质量好.混合溶剂萃取茶油机理表明:茶油在石油醚-95%甲醇体系两相中分配系数为527.03,石油醚-甲醇溶液提取茶油籽枯饼中茶油和茶皂素是可行的.

英文摘要:

The tea oil and tea saponin were simultaneously extracted from camellia oleifera cake with two-phase solvent of petroleum ether and methanol solution, and mechanism of the mixed solvent to extract tea oil was discussed. The methanol concentration, mixed solvent dosage, the ratio between the solvent extraction, extraction temperature and extraction time on the extraction effect were analyzed to confirm that the best process parameters was 90 % methanol concentration, solid-liquid mass ratio was 1∶3, hydrocarbon alcohol mass ratio was 1∶1, extraction temperature was 50 ℃, extraction time was 90 min, and tea oil yield was 8.42%, the tea saponin yield was 7.01 % after being extracted twice. The results show that the coarse tea oil is yellow in colour with black,with freezing point being-2 ℃, acid value being 6.489 mg/g (KOH), saponification value being199.821 mg/g (KOH) and iodine value being 78.616 g / (100 g). Unsaturated fatty acid content in the coarse tea oil is as high as 85.006%, and the quality is good. Mechanism of the mixed solvent to extract tea oil shows that partition coefficient of tea oil in two phase system of petroleum ether and 95 % methanol is 527.03, and the process of two-phase solvent of petroleum ether and methanol solution extracting tea oil and tea saponin from camellia oleifera seed cake is feasible.

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期刊信息
  • 《有色金属科学与工程》
  • 中国科技核心期刊
  • 主管单位:江西理工大学
  • 主办单位:江西理工大学 江西省有色金属学会
  • 主编:邱延省
  • 地址:江西省赣州市红旗大道86号江西理工大学行政楼6楼
  • 邮编:341000
  • 邮箱:jxys@chinajournal.net.cn
  • 电话:0797-8312555 8312211
  • 国际标准刊号:ISSN:1674-9669
  • 国内统一刊号:ISSN:36-1311/TF
  • 邮发代号:
  • 获奖情况:
  • 2012年荣获教育部第四届中国高校特色科技期刊奖、...,2010年获"江西省科技期刊评估优秀期刊","全国首届《CAJ-CD规范》执行优秀奖期刊"等
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),波兰哥白尼索引,中国中国科技核心期刊
  • 被引量:1630