一系列不对称的 monoimidazolium 基于 dihydroboronium 的离子的液体(IL ) 从 amine-boranes 被综合。所有产生 IL 被 1 H 和 13 C NMR,红外光谱学,元素的分析或高分辨率集中光谱。与对称的 bisimidazolium 相比,基于 dihydroboronium 的 IL,有更短的点火延期的展出改进性质预定的这些新 IL (标志) ,更高的密度,和更低的阶段转移作为绿燃料显示出有希望的申请潜力的温度。
A series of asymmetric monoimidazolium dihydroboronium-based ionic liquids (ILs) were synthesized from amine-boranes. All the resulting ILs were fully characterized by 1H and 13C NMR, IR spectroscopy, elemental analysis or high resolution mass spectrum. Compared with the symmetric bisimidazolium dihydroboronium-based ILs, these new ILs exhibited improved properties with shorter ignition delay times (IDs), higher densities, and lower phase transition temperature showing the promising application potential as green propellants. A series of asymmetric monoimidazolium dihydroboronium-based ionic liquids (ILs) were synthesized from amine-boranes. All the resulting ILs were fully characterized by 1H and 13C NMR, IR spectroscopy, elemental anal- ysis or high resolution mass spectrum. Compared with the symmetric bisimidazolium dihydroboronium-based ILs, these new ILs exhibited improved properties with shorter ignition delay times (IDs), higher densities, and lower phase transition temperature showing the promising application potential as green propellants.