中文摘要：

采用常规溶液聚合法制备出一种初粘力、180°剥离强度俱佳的丙烯酸酯PSA（压敏胶）,分别考察了乙酰丙酮铝（Al-acac）交联剂、聚合级多异氰酸酯类（M-75）交联剂和热膨胀型微球粉（膨胀粉）对PSA粘接性能的影响。研究结果表明：当w（Al-acac）=0.100%-0.175%（相对于PSA质量而言）时,PSA的持粘力为10-26 h;当w（Al-acac）≥0.200%时,PSA因出现凝胶而无法涂布。当w（M-75）=1.0%（相对于PSA质量而言）时,PSA的综合粘接性能相对最佳;当w（M-75）=1.0%、w（膨胀粉）=3%（相对于PSA质量而言）时,保护胶片经7 d以上的熟成后,其冷热剥离性均可达到无残胶的使用要求。

英文摘要：

An acrylate PSA （pressure sensitive adhesive） with good initial tack and 180° peeling strength was prepared by conventional solution polymerization. The influences of acetyl acetone aluminium （Al-acac） erosslinker, polymerization grade-polyisocyanate （M-75） crosslinker, and thermal expansion type mierospheres powder （expansion powder） on bonding properties of PSA were respectively investigated. The research results showed that the hold tack of PSA was 10-26 h when mass fraction of Al-acac was 0.100%-0.175% in PSA. The PSA couldn＇ t be coated by gel when mass fraction of Al-acac was not less than 0.200%. The combination property of PSA was relatively best when mass fraction of M-75 was 1.0% in PSA. The cold and hot peeling of protection film, which was ripened above 7 d, could all meet the application requirement without adhesive residue when mass fractions of M-75 and expansion powder were 1.0% and 3% respectively in PSA.