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Optical Properties of Nd^3+ in Nd(DBM)3Phen-doped Poly(methyl methacrylate)
  • ISSN号:1674-0068
  • 期刊名称:《化学物理学报》
  • 时间:0
  • 分类:O634[理学—高分子化学;理学—化学] O644.1[理学—物理化学;理学—化学]
  • 作者机构:[1]Department of Physics, Fujian Normal University, Fuzhou 350007, China, [2]Department of Physics, University of Science and Technology of China, Hefei 230025, China, [3]Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230025, China
  • 相关基金:ACKN0WLEDGMENT This work was supported by the National Natural Science Foundation of China (No.90201013), the Natural Science Foundation of Fujian Province of China (No.A0510014), and the Science Foundation of the Educational Department of Fujian Province of China (No JB03151 and JB04246).
中文摘要:

Nd (DBM )3做 Phen (DBM 是 dibenzoylmethane, Phen 是 phenanthroline ) polymethyl methacrylate (PMMA ) 被准备。光吸收,刺激和排放系列在 Nd (DBM )3Phen 药 PMMA 为 Nd 3+ 被分析。用 Judd-Ofelt 理论,吸收光谱被分析。Nd (DBM )3做 Phen 的 polymethyl methacrylate 被计算是 2= 20.97 ×; 10 20 厘米 2,4= 3.42 ×; 10 20 厘米 2,6= 2.90 ×; 10 20 厘米 2 。放射的一生(631

英文摘要:

Nd(DBM)3Phen-doped (DBM is dibenzoylmethane and Phen is phenanthroline) polymethyl methacrylate (PMMA) is prepared. Optical absorption, excitation and emission spectra were analyzed for Nd^3+ in Nd(DBM)3Phen-doped PMMA. Using the Judd-Ofelt theory, the absorption spectrum was analyzed. The Judd-Ofelt(J-O) intensity parameters of Nd(DBM)3Phen-doped polymethyl methacrylate were calculated to be Ω2 = 20.97 × 10^-20 cm^2, Ω4= 3.42 × 10^-20 cm^2, Ω6 = 2.90 × 10^-20 cm^2. The radiative lifetime (631 μs) of the excited 4F3/2 level is given. The stimulated emission cross-sections and the fluorescence branch ratios for the ^4F3/2 →^4Ij′ transitions are also evaluated. Analysis reveals that Nd(DBM)3Phen-doped PMMA is promising for application in polymer optical fibers and planar waveguides.

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期刊信息
  • 《化学物理学报》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国物理学会
  • 主编:杨学明
  • 地址:合肥中国科学技术大学
  • 邮编:230026
  • 邮箱:cjcp@ustc.edu.cn
  • 电话:0551-3601122
  • 国际标准刊号:ISSN:1674-0068
  • 国内统一刊号:ISSN:34-1295/O6
  • 邮发代号:26-62
  • 获奖情况:
  • 1998年获安徽省优秀科技期刊一等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:4282