综述了近年来过渡金属催化氮杂二环烯烃的开环反应的研究进展,重点讨论了过渡金属催化剂的种类、亲核试剂的类型、配体、底物氮杂二环烯烃及其衍生物的结构、溶剂和添加剂等因素对开环反应的影响,并对开环反应的可能的机理进行了讨论.
The recent progress in transition metal-catalyzed ring-opening reactions of azabicyclic alkenes was reviewed focused on the influence of the types of transition metal catalysts,nucleophiles,ligands,the structures of azabicyclic alkenes and its derivatives,solvents and additives on the ring-opening reactions.Moreover,the possible mechanisms of the ring-opening reactions were also discussed.