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贵州天桥铅锌矿床分散元素赋存状态及规律
  • ISSN号:1000-4734
  • 期刊名称:《矿物学报》
  • 时间:0
  • 分类:P571[天文地球—矿物学;天文地球—地质学]
  • 作者机构:[1]中国科学院地球化学研究所矿床地球化学国家重点实验室,贵州贵阳550002, [2]中国科学院研究生院,北京100049
  • 相关基金:国家重点基础研究发展计划(973计划)课题(2007CB411402);国家自然科学基金项目(40573036)
中文摘要:

利用电子探针(EPMA)、电感耦合等离子质谱(ICP-MS)等分析了天桥铅锌矿床矿石矿物中分散元素的含量、赋存状态及规律,结果表明分散元素在该矿床中含量达到了综合利用评价指标,有的甚至达到了工业品位(如Cd等);这些分散元素可能以类质同象的形式赋存在硫化物矿物中,其规律为Ga、Cd、In等赋存在闪锌矿中,Ce、Tl等赋存在方铅矿中,黄铁矿中分散元素富集低;在不同颜色闪锌矿中,Ca、Cd富集规律表现为浅色闪锌矿〉中色闪锌矿〉黑色闪锌矿,而Ge、Tl、In、Se富集表现出中色闪锌矿相对高于浅色及黑色闪锌矿;同标本中,不同颜色闪锌矿的Ce、In富集规律在还显示浅色闪锌矿〉中色闪锌矿〉黑色闪锌矿,而Ga、Tl、Cd、Se富集规律呈现中色闪锌矿相对高于浅色及黑色闪锌矿。Ga/In、Zn/Cd等参数指示出矿床成因类型可能为热液-沉积-改造。

英文摘要:

In this study, contents, occurrence states and regularities of the dispersed elements in ore minerals of Tianqiao Pb-Zn ore deposit were analyzed by using the methods of Electron Probe Microanalysis (EPMA) and Inductively Coupled Plasma Mass Spectrum (ICP-MS). The results showed that the contents of dispersed elements in Tianqiao Pb-Zn ore deposit had arrived at the level of comprehensive utilization, and some elements had even reached production grade (such as Cd, etc). The occurrence states of the dispersed elements may-be allomerism in the sulfide minerals. Ga, Cd, In, etc, are distributed in sphalerite, and Ge, Tl, etc, are distributed in galena, and all of the elements dispersed elements in pyrite are low. The concentrations of Ga, Cd in sphalerite are according the order of lightcoloured sphalerite 〉 mesocratic sphalerite 〉 black sphalerite, and the concentrations of Ge, TI, In, Se in mesocratic sphalerite are higher than those in lightcoloured and black sphalerite. In the the same sample, the concen- trations of Ge, In are according the order of lightcoloured part 〉 mesocratic part 〉 black part, and the concentra- tions of Ga, TI, Cd, Se in mesocratic part are higher than lightcoloured and black parts. The ratios of the Ga/In, Zn/Cd, etc indicate the metallogenetic deposit might be hydrothermal-sedimentogenic- diplogenetic- regenerated.

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期刊信息
  • 《矿物学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院地球化学研究所 中国矿物岩石地球化学学会
  • 主编:胡瑞忠
  • 地址:贵州省贵阳市观山湖区林城西路99号
  • 邮编:550081
  • 邮箱:kwxb@ms.gyig.ac.cn
  • 电话:0851-5891352
  • 国际标准刊号:ISSN:1000-4734
  • 国内统一刊号:ISSN:52-1045/P
  • 邮发代号:66-17
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:10998