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干压法制备LSM-YSZ阴极支撑电解质薄膜
  • 期刊名称:电源技术
  • 时间:0
  • 页码:351-354
  • 语言:中文
  • 分类:TM911.4[电气工程—电力电子与电力传动]
  • 作者机构:[1]中国矿业大学(北京)化学与环境工程学院煤气化燃料电池研究中心,北京100083
  • 相关基金:国家自然科学基金青年科学基金资助项目(20806088); 中国矿业大学(北京)SRTP资助项目(091219y)
  • 相关项目:直接甲烷固体氧化物燃料电池钙钛矿型阳极材料的研究
中文摘要:

采用甘氨酸-硝酸盐溶液燃烧法制备了粒度均匀、纯钙钛矿结构的La0.75Sr0.20MnO3-δ(LSM)阴极粉体。研究表明LSM阴极与(ZrO2)0.87(Sc2O3)0.11(Mn2O3)0.02(11ScSZ-2Mn2O3)电解质在1350℃以下时具有良好的化学相容性。以LSM-YSZ(氧化钇稳定氧化锆)为阴极,添加碳黑作造孔剂调节阴极的收缩率和孔隙率,采用干压法,在1250℃下共烧结制备了适宜孔结构和孔隙率的LSM-YSZ阴极支撑11ScSZ-2Mn2O3致密电解质薄膜。这种廉价、方便的干压、低温共烧结制备方法有助于推动阴极支撑型固体氧化物燃料电池(SOFC)的发展。

英文摘要:

La0.75Sr0.20MnO3-δ(LSM) powder with pure perovskite structure and uniform particle size was synthesized by glycine-nitrate solution combustion method. The investigations show that LSM cathode has good chemical compatibility with (ZrO2)0.87(Sc2O3)0.11(Mn2O3)0.02 (11ScSZ-2Mn2O3) electrolyte below 1 350 ℃. By adding carbon black as the pore former, the sintering shrinkage and porosity of LSM-YSZ (yttria stabilized zirconia) can be tailored. Dense 11ScSZ-2Mn2O3 electrolyte thin films supported on LSM-YSZ cathodes with a suitable porosity and pore structure were successfully fabricated by dry press technique and subsequent sintering at 1 250 ℃ . This dry-pressing combined with low-temperature co-sintering method is convenient and cost-effective, which facilitates the development of cathode-supported solid oxide fuel cell (SOFC).

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