π共轭有机氟硼络合物作为重要的荧光染料之一,以其较高的荧光量子产率和较大的摩尔吸光系数、良好的化学和光学稳定性备受关注,在有机合成、药物化学、新型材料、生命科学等领域应用广泛.本文综述了近年来π共轭有机氟硼络合物的合成研究,主要是N,N二齿、O,O二齿和N,O二齿类络合物,介绍了一些重要化合物的结构特点、主要性能及应用情况.
π-conjugated organic fluoroboron complexes, as a kind of important fluorophores, have been the focus of in- tense research for their higher quantum yields, larger extinction coefficients, outstanding chemo-stability and photo stabi- lity in recent years. They have been widely used in various fields, such as organic synthesis, pharmaceutical chemistry, new material and bioscience. This paper reviews the synthesis of some novel π-conjugated organic fluoroboron complexes, mainly including N, N-bidentates, 0,0-bidentates and N, O-bidentates. Some important complexes were introduced on their structure features, main characteristics and applications.