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中文摘要：
三氟甲硫基由于具有较强的吸电子性和极高的亲脂性,使得含三氟甲硫基的化合物在医药、农药以及材料等领域发挥着重要的作用.从有机氟化学的发展历程来看,三氟甲硫基化反应是继三氟甲基化反应后的又一重要研究课题,受到化学家的广泛关注.重点论述了近5年来国内外学者在直接三氟甲硫基化反应的研究成果,并讨论了三氟甲硫基化反应所面临的一些挑战.
英文摘要：
Compounds containing trifluoromethylthio group（SCF3） play an important role in pharmaceuticals, agrochemicals and materials due to its strong electron-withdrawing effect and extremely high lipophilicity. Very recently, trifluoromethylthiolation has received a great attention. In this review, the new progress of direct trifluoromethylthiolation is described. Furthermore, the synthetic challenge for trifluoromethylthiolation is also discussed.
同期刊论文项目
同项目期刊论文
Iron-Catalyzed Cross-Coupling Reactions between Arylzinc Reagents and Alkyl Halides Bearing beta-Flu
Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkynes and Aryl Boronic Acids Using (Tr
Synthesis of gamma-Monofluorinated Goniothalamin Analogues via Regio- and Stereoselective Ring-Openi
Synthesis of Trifluoromethylated and gem-Difluoromethylenated Biologically Interesting Compounds fro
Copper-catalyzed three-component oxytrifluoromethylation of alkenes with sodium trifluoromethanesulf
4-CF3-ezetimibe analogs: design, synthesis, and biological evaluation of cholesterol absorption inhi
Copper-Mediated Oxidative Cross-Coupling Reaction of Terminal Alkynes with alpha-Silyldifluoromethyl
Direct Introduction of Ethoxycarbonyldifluoromethyl-Group to Heteroarenes with Ethyl Bromodifluoroac
Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfu
Copper-Catalyzed Aerobic Oxidative Trifluoromethylation of H-Phosphonates Using Trimethyl(trifluorom
Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental
Palladium-catalyzed direct alpha-arylation of alpha-fluoroketones: A straightforward route to alpha-
Lewis acid-catalyzed regioselective synthesis of chiral alpha-fluoroalkyl amines via asymmetric addi
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