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活性炭纤维对有机废水的吸附研究
  • ISSN号:1009-2455
  • 期刊名称:《工业用水与废水》
  • 时间:0
  • 分类:X703.5[环境科学与工程—环境工程]
  • 作者机构:东南大学能源与环境学院东南大学能源热转换及其过程测控教育部重点实验室,南京210096
  • 相关基金:国家自然科学基金项且(51576048)
中文摘要:

以碱性木质素为原料通过静电纺丝法制备得到活性炭纤维。采用比表面积及孔径分析仪对活性炭纤维进行表征分析,同时以该活性炭纤维为吸附剂对甲苯、甲醇和丙酮3种有机废水进行吸附法净化处理,结果表明该活性炭纤维的比表面积达到807.77m2/g,孔容为0.484cm7g。中值孔径为2.11nm:活性炭纤维对3种有机废水具有一定的吸附净化效果,3种有机物中甲苯的吸附最快,吸附量最大;对甲苯、甲醇和丙酮的最大吸附量分别是229.12、156.68和103.34mg/g。3种有机废水的吸附动力学分析结果表明:活性炭纤维对甲苯、甲醇和丙酮的吸附数据分别与准二阶模型、Werber-Morris模型和准一阶模型具有较好的拟合相关性。

英文摘要:

With alkaline lignin as raw material, activated carbon fiber was prepared using electrostatic spinning method. The characteristics of the activated carbon fiber were analyzed by specific surface area and pore diameter analyzer; meanwhile, the said activated carbon fiber was used as adsorbent to purify toluene, methanol and acetone containing organic wastewater. The results showed that, the specific surface area of the activated carbon fiber reached 807.77 mZ/g, the pore volume was 0.484 cm3/g, the medium pore size was 2.11 nm. It could be seen that, activated carbon fiber had certain purification effect on the above three kinds of organic wastewater, the speed of the adsorption on toluene was the fastest and the adsorption capacity of it was also the biggest. Besides, the maximum adsorption capacity for toluene, methanol and acetone were 229.12, 156.68 and 103.34 mg/g respectively. The analysis results of the adsorption kinetics of the above three kinds of organic wastewater showed that, the adsorption data of toluene, methanol and acetone by activated carbon fiber possessed preferable fitting correlations with pseudo-second model, Werber-Morris model and pseudo-first model respectively.

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期刊信息
  • 《工业用水与废水》
  • 中国科技核心期刊
  • 主管单位:东华工程科技股份有限公司
  • 主办单位:东华工程科技股份有限公司
  • 主编:马强
  • 地址:安徽省合肥市望江东路70号
  • 邮编:230024
  • 邮箱:cniww@vip.163.com
  • 电话:0551-63626465 63621791
  • 国际标准刊号:ISSN:1009-2455
  • 国内统一刊号:ISSN:34-1204/TQ
  • 邮发代号:26-159
  • 获奖情况:
  • 全国石油和化工优秀期刊一等奖,安徽省优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国剑桥科学文摘,中国中国科技核心期刊
  • 被引量:9410