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Self-assembling organomodified Co/Al based layered double hydroxides (LDH) via one-step route
  • ISSN号:1003-6326
  • 期刊名称:《中国有色金属学报:英文版》
  • 时间:0
  • 分类:TQ330.381[化学工程—橡胶工业] O614.31[理学—无机化学;理学—化学]
  • 作者机构:[1]Center for Degradable and Flame-Retardant Polymeric Materials (ERCEPM-MoE), College of Chemistry, Sichuan University Chengdu 610064, China, [2]State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610064, China, [3]Leibniz Institute of Polymer Research, Dresden D01069, Germany
  • 相关基金:Project(50703026) supported by the National Natural Science Foundation of China; project(F/4285-1) supported by International Foundation for Science (IFS); project(20080440182, 200902615) supported by China Postdoctoral Science Foundation; project supported by Guest-Scientist Research Fellowship granted by Leibniz Institute of Polymer Research Dresden, Germany
中文摘要:

经由一步舞线路的自我装配的 organomodified Co/Al-layered 双氢氧化物(LDH ) 的准备被学习。普通表面活化剂,钠 dodecylbenzenesulfonate (DBS ) ,作为一个器官的修饰词被采用。自我装配的设置的器官的 Co/Al-LDH 的行为和结构被 FTIR, SEM,蜡,元素分析和 TGA 调查。由布拉格方程在 WAXS 之上基于结果和计算,为器官的 Co/Al-LDH 的夹层距离(d 价值) 从 0.75 nm 被扩大到 3.10 nm,证明自我装配的行为成功地被执行了。就从 SEM 的观察而言,产品显示出分层的结构的器官的 Co/Al-LDH 的形态学。另外, FTIR,元素分析和 TGA 分析证明修饰词被设置进 Co/Al-LDH 的画廊。因为为 nanofiller 的器官的修正被认为在使用它进聚合物前必要, organomodified Co/Al-LDH 的成功的准备将对新奇 polymer/LDH nanocomposite 的准备和调查显著地有益。

英文摘要:

The preparation of self-assembling organomodified Co/Al-layered double hydroxide (LDH) via one-step route was studied A common surfactant, sodium dodecylbenzenesulfonate (DBS), was employed as an organic modifier. The behavior and structure of self-assembled intercalated organic Co/Al-LDH were investigated by FTIR, SEM, WAXS, element analysis and TGA. Based upon the WAXS results and calculation by Bragg equation, the interlayer distance (d value) for organic Co/Al-LDH is enlarged from 0.75 nm to 3.10 nm, showing that the self-assembling behavior has been carried out successfully. Considering the observation from SEM, the product shows the morphology of organic Co/Al-LDH of a layered structure. In addition, FTIR, element analysis and TGA analysis show that the modifier is intercalated into the gallery of the Co/Al-LDH. Since organic modification for nanofiller is deemed to be necessary before applying it into polymer, the successful preparation of organomodified Co/Al-LDH will be significantly beneficial to the preparation and investigation of novel polymer/LDH nanocomposite.

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期刊信息
  • 《中国有色金属学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国有色金属学会
  • 主编:黄伯云
  • 地址:中国长沙中南大学
  • 邮编:410083
  • 邮箱:f-xsxb@csu.edu.cn
  • 电话:0731-88830949
  • 国际标准刊号:ISSN:1003-6326
  • 国内统一刊号:ISSN:43-1239/TG
  • 邮发代号:42-317
  • 获奖情况:
  • 国家“双百”期刊,第二届全国优秀科技期刊评比二等奖,中国有色金属工业总公司优秀科技期刊一等奖
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  • 被引量:1159